Phenylmercuric acetate

ALDRICH/P27127 - 97%

Synonym: Phenylmercury acetate; Mercury phenyl acetate

CAS Number: 62-38-4
Empirical Formula (Hill Notation): C₈H₈HgO₂
Molecular Weight: 336.74
EC Number: 200-532-5
MDL Number: MFCD00008691
Linear Formula: C₆H₅HgOCOCH₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-P27127-25G	25 g	$60.30 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
form	powder
InChI	1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1
InChI key	XEBWQGVWTUSTLN-UHFFFAOYSA-M
mp	148-151 °C (lit.)
SMILES string	CC(=O)O[Hg]c1ccccc1

Application:	Phenylmercuric acetate (PMA) can react with a palladium salt such as palladium acetate to form an arylpalladium salt in situ, which then reacts with primary or secondary allylic alcohols to produce 3-aryl aldehydes. It can also be used in the multi-step synthesis of 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl thiol via Floyd′s pathway.
Packaging:	25 g in glass bottle

Symbol	GHS05,GHS06,GHS08,GHS09
Signal word	Danger
Hazard statements	H301 - H314 - H372 - H410
Precautionary statements	P260 - P273 - P280 - P301 + P310 + P330 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	T,N
Risk Statements	25-34-48/24/25-50/53
Safety Statements	23-24/25-37-45-60-61
RIDADR	UN 1674 6.1 / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
mp	148-151 °C (lit.)
UNSPSC	12352103

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