Sulfur trioxide pyridine complex
ALDRICH/S7556 - 97%
Synonym: NSC 75831; Pyridine sulfur trioxide complex
CAS Number: 26412-87-3
Empirical Formula (Hill Notation): C5H5NO3S
Molecular Weight: 159.16
EC Number: 247-683-3
MDL Number: MFCD00012437
Linear Formula: C5H5NO3S
Product Type: Chemical
assay | 97% |
InChI | 1S/C5H5N.O3S/c1-2-4-6-5-3 |
InChI key | UDYFLDICVHJSOY-UHFFFAOYSA |
reaction suitability | reagent type: oxidant |
SMILES string | O=S(=O)=O.c1ccncc1 |
Application: | • Sulfation agent Reactant for: • Preparation of azido anologs of pregnanolone • Sulfate esters of morphine derivatives • Gold nanoparticles capped with sulfate-ended ligands as anti-HIV agents |
Application: | Sulfur trioxide-pyridine (SO3-py) complex can be used to convert the allylic or benzylic hydroxyl group of compounds such as geraniol, farnesol, and 1-indanol into sulfate monoester, which is a good leaving group. This method is highly useful in the total synthesis of sesquiterpenes. As a sulfating agent, SO3-py complex can be used for the preparation of sulfated-chitins, sulfated hyaluronan (HyaS) derivatives and sulfated starch. |
Packaging: | 1 kg in glass bottle |
Packaging: | 25, 100 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H302 - H315 - H319 |
Precautionary statements | P264 - P270 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 |
Hazard Codes | C |
Risk Statements | 22-34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3261 8 / PGII |
WGK Germany | WGK 3 |
Purity | 97% |
UNSPSC | 12352303 |