Trimethylsulfonium iodide
ALDRICH/T80489 - 98%
Synonym: Trimethyl-λ[3]-sulfane hydroiodide; Trimethylsulphonium iodide
CAS Number: 2181-42-2
Empirical Formula (Hill Notation): C3H9IS
Molecular Weight: 204.07
EC Number: 218-555-4
MDL Number: MFCD00011632
Linear Formula: (CH3)3S(I)
Product Type: Chemical
assay | 98% |
InChI | 1S/C3H9S.HI/c1-4(2)3;/h1- |
InChI key | VFJYIHQDILEQNR-UHFFFAOYSA |
mp | 215-220 °C (lit.) |
reaction suitability | reaction type: C-C Bond Formation |
SMILES string | [I-].C[S+](C)C |
Application: | Treatment with strong base yields the dimethylsulfonium methylide which reacts in-situ with the carbonyl group of ketones to form epoxides or allylic alcohols. |
General description: | Trimethylsulfonium iodide is commonly used as a methylating agent in organic synthesis. |
Packaging: | 25, 100 g in poly bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 98% |
mp | 215-220 °C (lit.) |
UNSPSC | 12352101 |