L-(−)-Malic acid
SIAL/02288 - ReagentPlus®, ≥99%
Synonym: (S)-(−)-2-Hydroxysuccinic acid; L-Hydroxybutanedioic acid
CAS Number: 97-67-6
Empirical Formula (Hill Notation): C4H6O5
Molecular Weight: 134.09
EC Number: 202-601-5
MDL Number: MFCD00064213
Linear Formula: HO2CCH2CH(OH)CO2H
Product Type: Chemical
assay | ≥99% |
cation traces | Fe: ≤10 mg/kg |
ign. residue | ≤0.1% (as SO4) |
impurities | ≤0.3% water |
InChI | 1S/C4H6O5/c5-2(4(8)9)1-3( |
InChI key | BJEPYKJPYRNKOW-REOHCLBHSA |
mp | 101-103 °C (lit.) |
optical activity | [α]20/D −30±2°, c = 5.5% in pyridine |
product line | ReagentPlus® |
Quality Level | 100 ![]() |
SMILES string | O[C@@H](CC(O)=O)C(O)=O |
Application: | • As a carboxylate ligand in the preparation of a variety of chiral metal malates and coordination polymers. • In the preparation of poly(malic acid), which is a biodegradable, bioabsorbable and water-soluble polymer. • As a key ingredient in the total synthesis of (+)-australine, (+)-brasilenyne, epothilones B and D. |
Legal Information: | ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC |
Symbol | ![]() |
Signal word | Warning |
Hazard statements | H319 |
Precautionary statements | P264 - P280 - P305 + P351 + P338 - P337 + P313 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 1 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥99% |
mp | 101-103 °C (lit.) |
UNSPSC | 51113400 |