Phosphorus, red
SIAL/04004 - ≥97.0%
Synonym: P
CAS Number: 7723-14-0
Empirical Formula (Hill Notation): P
Molecular Weight: 30.97
EC Number: 231-768-7
MDL Number: MFCD00133771
Linear Formula: P
Product Type: Chemical
assay | ≥97.0% |
autoignition temp. | 500 °F |
cation traces | Fe: ≤2000 mg/kg |
density | 2.34 g/mL at 25 °C (lit.) |
InChI | 1S/P |
InChI key | OAICVXFJPJFONN-UHFFFAOYSA |
mp | 416 °C (subl.) (lit.) |
Quality Level | 100 |
reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
reaction type: Heck Reaction | |
reaction type: Hiyama Coupling | |
reaction type: Negishi Coupling | |
reaction type: Sonogashira Coupling | |
reaction type: Stille Coupling | |
reaction type: Suzuki-Miyaura Coupling | |
reagent type: catalyst | |
resistivity | 10 μΩ-cm, 20°C |
SMILES string | [P] |
storage temp. | 2-8°C |
vapor density | 0.02 (vs air) |
vapor pressure | 0.03 mmHg ( 21 °C) |
1 mmHg ( 76.6 °C) |
Application: | Red phosphorus can be used as a: • Photocatalyst for the formation of H2 from water. • Catalyst in the synthesis of tris(2-pyridyl)phosphine by reacting with 2-bromopyridine in the presence of a base. • Flame retardant along with aluminum oxide in recycled poly(ethylene terephthalate). • Anode material in combination with carbon composites for sodium-ion batteries. |
General description: | Red phosphorus is the most common allotrope ofphosphorus due to its relative stability compared to white phosphorus. It has a variety of uses including, but notlimited to, use as a catalyst, battery anode, flame retardant, and igniter. |
Symbol | GHS02 |
Signal word | Warning |
Hazard statements | H228 - H412 |
Precautionary statements | P210 - P240 - P241 - P273 - P280 - P370 + P378 |
Hazard Codes | F |
Risk Statements | 11-16-52/53 |
Safety Statements | 7-43-61 |
RIDADR | UN1338 - class 4.1 - PG 3 - Phosphorus, amorphous |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥97.0% |
mp | 416 °C (subl.) (lit.) |
Density | 2.34 g/mL at 25 °C (lit.) |
Storage Temp. | 2-8°C |
UNSPSC | 12141909 |