trans-Permethrin-(phenoxy-d₅)

SIAL/08979 - analytical standard

Synonym: trans-Permethrin-d₅; [3-(Phenoxy-d₅)phenyl]methyl trans-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate

Empirical Formula (Hill Notation): C₂₁D₅H₁₅Cl₂O₃
Molecular Weight: 396.32
Linear Formula: C₂₁D₅H₁₅Cl₂O₃
Product Type: Chemical

application(s)	agriculture
assay	≥98.0% (HPLC)
format	neat
grade	analytical standard
product line	PESTANAL^®
Quality Level	100
shelf life	limited shelf life, expiry date on the label
SMILES string	ClC(Cl)=CC(C1(C)C)C1C(OCC2=CC=CC(OC3=C([2H])C([2H])=C([2H])C([2H])=C3[2H])=C2)=O
storage temp.	2-8°C

Application:	Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.
General description:	trans-Permethrin-(phenoxy-d₅) is an isotope-labeled analog of the trans-isomeric form of the pyrethroid insecticide permethrin, wherein the phenoxy protons are replaced by deuterium.
Legal Information:	PESTANAL is a registered trademark of Sigma-Aldrich International GmbH