Aniline
SIAL/132934 - ReagentPlus®, 99%
Synonym: Aminobenzene; Benzenamine
CAS Number: 62-53-3
Empirical Formula (Hill Notation): C6H7N
Molecular Weight: 93.13
EC Number: 200-539-3
MDL Number: MFCD00007629
Linear Formula: C6H5NH2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 132934-500ML.
| assay | 99% |
| autoignition temp. | 1139 °F |
| bp | 184 °C (lit.) |
| density | 1.022 g/mL at 25 °C (lit.) |
| expl. lim. | 11 % |
| form | liquid |
| InChI | 1S/C6H7N/c7-6-4-2-1-3-5-6 |
| InChI key | PAYRUJLWNCNPSJ-UHFFFAOYSA |
| mp | −6 °C (lit.) |
| pH | 8.8 (20 °C, 36 g/L) |
| product line | ReagentPlus® |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | Nc1ccccc1 |
| solubility | water: soluble |
| vapor density | 3.22 (185 °C, vs air) |
| vapor pressure | 0.7 mmHg ( 25 °C) |
| Application: | Aniline may be used in the preparation of azobenzene. |
| Biochem/physiol Actions: | The acute toxicity of aniline involves its activation in vivo to 4-hydroxyaniline and the formation of adducts with hemoglobin. In erythrocytes, this is associated with the release of iron and the accumulation of methemoglobin and the development of hemolytic anemia and inflammation of the spleen. Tumor formation is often observed in the spleen on prolonged administration. |
| General description: | Aniline is an aromatic amine. It is a key industrial intermediate, widely employed for the preparation of dyes, rubber, resins and polymers. Complete vibrational assignements of aniline and its deuterated forms (aniline-NHD and aniline-ND2) have been reported.1 p-aminodiphenylamine (ADPA) has been reported to be formed as a major intermediate during the electropolymerizatrion of aniline. Its viscosity has been reported to be 3.1457cp at 30°C. Quantitative transformation of nitrobenzene to aniline has been carried out by employing functionalized plasmonic Au/TiO2 photocatalyst along with a Ag co-catalyst. Aniline can be prepared from nitrobenzene, via hydrogenation in the presence of Cu, Ni, Pt, Pd and Au (catalyst). It can also be prepared by photocatalytic reduction of nitrobenzene in the presence of WO3-Ag hybrid nanowires. |
| Legal Information: | ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany |
| Packaging: | 18 L in steel drum |
| Packaging: | 2.5 L in glass bottle |
| Packaging: | 500 mL in glass bottle |
| Physical properties: | Material darkens in storage to reddish-brown with no loss in purity. |
| Symbol |     GHS05,GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H301 + H311 + H331 - H317 - H318 - H341 - H351 - H372 - H410 |
| Precautionary statements | P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338 |
| Hazard Codes | T,N |
| Risk Statements | 23/24/25-40-41-43-48/23/24/25-50-68 |
| Safety Statements | 26-27-36/37/39-45-46-61-63 |
| RIDADR | UN 1547 6.1 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 158.0 °F - closed cup |
| Flash Point(C) | 70 °C - closed cup |
| Purity | 99% |
| bp | 184 °C (lit.) |
| mp | −6 °C (lit.) |
| Density | 1.022 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |