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[Bis(trifluoroacetoxy)iodo]benzene

SIAL/15230 - purum, ≥95.0% (AT)

Synonym: BTI; Iodobenzene I,I-bis(trifluoroacetate); PIFA

CAS Number: 2712-78-9
Empirical Formula (Hill Notation): C10H5F6IO4
Molecular Weight: 430.04
EC Number: 220-308-0
MDL Number: MFCD00009672
Linear Formula: (CF3CO2)2IC6H5
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-15230-10G 10 g
 $94.00
1/EA		 Add To Favorites
45-15230-50G 50 g
 $0.00
1/EA
CALL FOR PRICE		 Add To Favorites

 

assay ≥95.0% (AT)
form solid
functional group fluoro
  iodo
grade purum
InChI 1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H
InChI key PEZNEXFPRSOYPL-UHFFFAOYSA-N
mp 121-125 °C (lit.)
  122-125 °C
Quality Level 200 
reaction suitability reagent type: oxidant
SMILES string FC(F)(F)C(=O)O[I](OC(=O)C(F)(F)F)c1ccccc1
Application: Reactant or reagent for:
• Pummerer-like reactions
• Chemoselective deprotection of dimethoxybenzyl ethers
• Mediating oxidative cycloisomerization
• Tosyloxylation of anilides
Other Notes: Reagent for dehydrogenation and oxidation reactions, review; New reagent for the direct conversions of amides to amines (Hofmann-type rearrangement) and key substance for carboxyterminal peptide sequencing; Smooth dethioacetalization to the carbonyls
Purity ≥95.0% (AT)
mp 121-125 °C (lit.); 122-125 °C
UNSPSC 12352002

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