Sodium methoxide solution
SIAL/156256 - 25 wt. % in methanol
Synonym: Sodium methylate
CAS Number: 124-41-4
Empirical Formula (Hill Notation): CH3NaO
Molecular Weight: 54.02
MDL Number: MFCD00012179
Linear Formula: CH3ONa
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 156256-1L.
| autoignition temp. | 878 °F |
| concentration | 25 wt. % in methanol |
| density | 0.945 g/mL at 25 °C |
| form | liquid |
| InChI | 1S/CH3O.Na/c1-2;/h1H3;/q- |
| InChI key | WQDUMFSSJAZKTM-UHFFFAOYSA |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | [Na+].C[O-] |
| vapor density | 1.1 (vs air) |
| vapor pressure | 50 mmHg ( 20 °C) |
| 96 mmHg ( 25 °C) |
| Application: | A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state. |
| Application: | Sodium methoxide solution has been used in the synthesis of NO-containing nanoparticles (SNO-NP). |
| General description: | The product is 25wt.% solution of sodium methoxide in methanol. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF (Dimethylformamide) to afford arenes. |
| Packaging: | 1, 2.5 L in glass bottle |
| Packaging: | 18 L in steel drum |
| Packaging: | 25 mL in glass bottle |
| Symbol |     GHS02,GHS05,GHS06,GHS08 |
| Signal word | Danger |
| Hazard statements | H225 - H251 - H290 - H301 + H311 + H331 - H314 - H370 |
| Precautionary statements | P210 - P235 - P280 - P301 + P310 + P330 - P303 + P361 + P353 - P305 + P351 + P338 + P310 |
| Hazard Codes | F,T |
| Risk Statements | 11-14-23/24/25-34-39/23/24/25 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN1289 - class 3 - PG 2 - Sodium methylate solutions |
| WGK Germany | WGK 2 |
| Flash Point(F) | 51.8 °F - closed cup - Solv |
| Flash Point(C) | 11 °C - closed cup - Solven |
| Supplemental Hazard Statements | EUH014 |
| Density | 0.945 g/mL at 25 °C |
| Refractive Index | n |
| UNSPSC | 12352100 |