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Boric anhydride

SIAL/15678 - puriss. p.a., ≥98% (T)

Synonym: Boron trioxide

CAS Number: 1303-86-2
Empirical Formula (Hill Notation): B2O3
Molecular Weight: 69.62
EC Number: 215-125-8
MDL Number: MFCD00011315
Linear Formula: B2O3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-15678-50G 50 g
$0.00
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45-15678-250G 250 g
$160.00
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45-15678-1KG 1 kg
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anion traces chloride (Cl-): ≤20 mg/kg
  sulfate (SO42-): ≤50 mg/kg
assay ≥98% (T)
cation traces Ag: ≤5 mg/kg
  Al: ≤50 mg/kg
  Ba: ≤5 mg/kg
  Bi: ≤5 mg/kg
  Ca: ≤10 mg/kg
  Cd: ≤5 mg/kg
  Co: ≤5 mg/kg
  Cr: ≤5 mg/kg
  Cu: ≤5 mg/kg
  Fe: ≤5 mg/kg
  K: ≤30 mg/kg
  Mg: ≤20 mg/kg
  Mn: ≤5 mg/kg
  Mo: ≤5 mg/kg
  Na: ≤200 mg/kg
  Ni: ≤5 mg/kg
  Pb: ≤30 mg/kg
  Sr: ≤5 mg/kg
  Tl: ≤10 mg/kg
  Zn: ≤5 mg/kg
density 2.46 g/mL at 25 °C (lit.)
form solid
grade puriss. p.a.
InChI 1S/B2O3/c3-1-5-2-4
InChI key JKWMSGQKBLHBQQ-UHFFFAOYSA-N
loss ≤3% loss on ignition, 900 °C
mp 450 °C (lit.)
Quality Level 100 
SMILES string O=BOB=O
vapor density >1 (vs air)
Application: Boric anhydride can be used as a boron precursor to synthesize:
• Boron carbon nitride nanosheet (BCN) by thermal condensation reaction with urea and melamine.
• Boron-doped reduced graphene oxide (B-rGO) via a chemical vapor deposition method.
It can also be used as an additive along with pinacol to synthesize 4-alkoxy-5-hydroxy-2-pentenoate derivatives by Pd-catalyzed reaction of α, β-unsaturated γ, δ-epoxy esters with various alcohols.
General description: Boric anhydride (Boron trioxide) is a colorless glassy hygroscopic mass having rhombic crystals. Its dissolution in water is a highly exothermic reaction and orthoboric acid is formed. It can be prepared by heating boric acid. It is used as flux in metallurgical processes. It has been reported as an inhibitor of crystallization.
Other Notes: Reagent for the decomposition of silicates by fusion
Purity ≥98% (T)
mp 450 °C (lit.)
Density 2.46 g/mL at 25 °C (lit.)
UNSPSC 12352300

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