Sulfuryl chloride
SIAL/157767 - 97%
CAS Number: 7791-25-5
Empirical Formula (Hill Notation): Cl2O2S
Molecular Weight: 134.97
EC Number: 232-245-6
MDL Number: MFCD00011451
Linear Formula: SO2Cl2
Product Type: Chemical
| assay | 97% |
| bp | 68-70 °C (lit.) |
| density | 1.665 g/mL at 20 °C (lit.) |
| form | liquid |
| InChI | 1S/Cl2O2S/c1-5(2,3)4 |
| InChI key | YBBRCQOCSYXUOC-UHFFFAOYSA |
| mp | −54 °C (lit.) |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | ClS(Cl)(=O)=O |
| vapor density | 4.7 (vs air) |
| vapor pressure | 100 mmHg ( 17.8 °C) |
| 105 mmHg ( 20 °C) |
| Application: | Sulfuryl chloride (SO2Cl2) may be used in the following studies: • Synthesis of α-chloroketones. • Regioselective (ortho-selective) chlorination of phenols. • Conversion of monocyclic allylic cis-1,2-diols to the corresponding trans-1,2-chlorohydrins. • Preparation of β-chlorotetrahydrofuran derivatives. Sulfuryl chloride may be used as an efficient reagent for the p-chlorination of phenols. |
| General description: | Sulfuryl chloride is a sulfur containing reagent. It is widely used for chlorination of various compounds, as it dissociates into sulfur dioxide and chlorine during reaction. Thus, it acts as a source of molecular chlorine for various aromatic chlorination reactions. Its chlorination reaction with dimethyl sulfide has been studied. Sulfuryl chloride may be used as an efficient reagent for the p-chlorination of phenols. |
| Packaging: | 1 kg in glass bottle |
| Packaging: | 25 g in glass bottle |
| Symbol |   GHS05,GHS06 |
| Signal word | Danger |
| Hazard statements | H314 - H330 - H335 |
| Precautionary statements | P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| Hazard Codes | C |
| Risk Statements | 14-34-37 |
| Safety Statements | 26-45 |
| RIDADR | UN1834 - class 8 - PG 1 - Sulphuryl chloride |
| WGK Germany | WGK 1 |
| Supplemental Hazard Statements | EUH014 |
| Purity | 97% |
| bp | 68-70 °C (lit.) |
| mp | −54 °C (lit.) |
| Density | 1.665 g/mL at 20 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352302 |