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Phosphorus trichloride

SIAL/157791 - ReagentPlus®, 99%

Synonym: Phosphorus(III) chloride

CAS Number: 7719-12-2
Empirical Formula (Hill Notation): Cl3P
Molecular Weight: 137.33
EC Number: 231-749-3
MDL Number: MFCD00011438
Linear Formula: PCl3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-157791-50G 50 g
$59.90
1/EA
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45-157791-250G 250 g
$73.20
1/EA
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45-157791-1KG 1 kg
$165.00
1/EA
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assay 99%
bp 74-78 °C (lit.)
density 1.574 g/mL at 20 °C (lit.)
form liquid
InChI 1S/Cl3P/c1-4(2)3
InChI key FAIAAWCVCHQXDN-UHFFFAOYSA-N
mp −112 °C (lit.)
product line ReagentPlus®
Quality Level 200 
refractive index n20/D 1.5148 (lit.)
SMILES string ClP(Cl)Cl
vapor density 4.75 (vs air)
vapor pressure 100 mmHg ( 20 °C)
  125 mmHg ( 25 °C)
  385 mmHg ( 55 °C)
Application: Phosphorus trichloride may be used in the preparation of following:
• alkylphosphonyl dichlorides
• benzidronate
• 4-(dibromomethyl)-substituted benzenes bearing a phosphorus functional group in the side chain
• dinucleoside phosphorochloridite
General description: Phosphorus trichloride is a slightly yellow or colorless fuming liquid, which finds applications in electrodeposition of metal on rubber and in the preparation of pesticides. It can undergo reaction with chlorine gas to form phosphorus pentachloride.
General description: Rotational spectra of phosphorus trichloride has been studied in the microwave region. Its reaction with unsaturated compounds in the presence of diacetyl peroxide has been reported.
Legal Information: ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Packaging: 1 kg in Sure/Seal™
Packaging: 50, 250 g in Sure/Seal™
Purity 99%
bp 74-78 °C (lit.)
mp −112 °C (lit.)
Density 1.574 g/mL at 20 °C (lit.)
Refractive Index n20/D 1.5148 (lit.)
UNSPSC 12352300

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