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Tetramethylammonium bromide

SIAL/195758 - 98%

Synonym: TMAB

CAS Number: 64-20-0
Empirical Formula (Hill Notation): C4H12BrN
Molecular Weight: 154.05
EC Number: 200-581-2
MDL Number: MFCD00011626
Linear Formula: (CH3)4N(Br)
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-195758-100G 100 g
$36.20
1/EA
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45-195758-500G 500 g
$130.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 195758-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 195758-500G

 

assay 98%
form solid
InChI 1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI key DDFYFBUWEBINLX-UHFFFAOYSA-M
mp >300 °C (lit.)
Quality Level 100 
SMILES string [Br-].C[N+](C)(C)C
Application: Tetrabutylammonium bromide may be used in the molten state in the following processes:
• Synthesis of (2S)-5-(3-phenyl-2-phthalimidylpropanoylamino)isophthalic acid.
• Synthesis of alkyl-substituted pyrroles in the absence of catalyst and organic solvent.
• Synthesis of dithioacetals from acetals by transthioacetalisation in a solvent free environment.
• Synthesis of polyamides (PAs) by the polymerization of terephthalic acid and diisocyanates.
• Catalyze the addition of thiols to conjugated alkenes.
• Dehydrochlorination of poly(vinyl chloride).
Application: Tetramethylammonium bromide may be used as a template in the synthesis of small colloidal zeolite Y nanocrystals.
General description: Tetrabutylammonium bromide is a quaternary ammonium compound that is widely used as a phase transfer catalyst. Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30°C). Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated.
General description: Tetramethylammonium bromide (TMABr) is a quaternary ammonium salt that is widely used as a phase transfer catalyst. Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30°C). Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated. Its impact on the first order rate constant values for the base hydrolysis of the following Fe(II) chelates has been investigated:




• bis(naphthylidene alanate) (nali)
• bis(naphthylidene phenylalanate) (nphali)
• bis(naphthylidene aspartate) (nasi)
• (naphthylidene histidinate) (nhi)
• bis(naphthylidenearginate) (nari)
Packaging: 100, 500 g in poly bottle
Symbol GHS06  GHS06
Signal word Danger
Hazard statements H300
Precautionary statements P301 + P330 + P331 + P310
Hazard Codes T
Risk Statements 25-36/37/38
Safety Statements 26-28-36-45
RIDADR UN 2811 6.1 / PGII
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 98%
mp >300 °C (lit.)
UNSPSC 12352100

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