2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine

SIAL/20025 - purum, ≥98.0% (GC)

Synonym: BEMP

CAS Number: 98015-45-3
Empirical Formula (Hill Notation): C₁₃H₃₁N₄P
Molecular Weight: 274.39
MDL Number: MFCD00043143
Linear Formula: C₁₃H₃₁N₄P
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-20025-1ML	1 mL	$138.00 1/EA		Add To Favorites
45-20025-5ML	5 mL	$658.00 1/EA		Add To Favorites
45-20025-25ML	25 mL	$2010.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	≥98.0% (GC)
bp	74 °C/0.03 mmHg (lit.)
density	0.948 g/mL at 25 °C (lit.)
form	liquid
grade	purum
InChI	1S/C13H31N4P/c1-8-17(9-2)18(14-13(3,4)5)15(6)11-10-12-16(18)7/h8-12H2,1-7H3
InChI key	VSCBATMPTLKTOV-UHFFFAOYSA-N
Quality Level	200
refractive index	n20/D 1.477
	n20/D 1.477 (lit.)
SMILES string	CCN(CC)P1(=NC(C)(C)C)N(C)CCCN1C

Application:	2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine (BEMP), a organic phosphorine base may be used in the following studies: • Synthesis of a 2,3-dihydrobenzo[1,4]dioxepin-5-one. • As catalyst in the alkylation reactions of carbon acids. • As organocatalyst in the controlled "immortal" ring-opening polymerization (iROP) of six-membered cyclic carbonates.
Application:	Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases
General description:	2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine (BEMP) is a phosphazene base. BEMP participates in the mild base catalyzed nucleophilic ring opening of N-sulfonyl aziridines. BEMP supported on polystyrene (PS-BEMP) has been reported as an efficient catalyst for the ring-opening of epoxides with phenols. BEMP is about 2000 times more basic and also much more sterically hindered than DBU (l,8-diazabicyclo[5.4.0]undecene).

Symbol	GHS05
Signal word	Danger
Hazard statements	H314
Precautionary statements	P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
Hazard Codes	C
Risk Statements	34
Safety Statements	26-36/37/39-45
RIDADR	UN 2920 3(8) / PGII
WGK Germany	WGK 3
Flash Point(F)	230.0 °F - closed cup
Flash Point(C)	110 °C - closed cup

Purity	≥98.0% (GC)
bp	74 °C/0.03 mmHg (lit.)
Density	0.948 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.477 (lit.); n20/D 1.477
UNSPSC	12352005

Choose a favorite list for this item:

Catalog Number	Description	Price

		$

Please choose a list :

Continue Shopping

Returns/Order support

Please fill out the form below if you want to request order support from Krackeler Scientific.