OXONE®, monopersulfate compound
SIAL/228036
Synonym: Potassium peroxymonosulfate
CAS Number: 70693-62-8
Empirical Formula (Hill Notation): HKO5S · 0.5HKO4S · 0.5K2O4S
Molecular Weight: 307.38
MDL Number: MFCD00040551
Linear Formula: KHSO5 · 0.5KHSO4 · 0.5K2SO4
Product Type: Chemical
concentration | >4.0% (active oxygen basis (by Na2S2O3, titration)) |
form | powder |
InChI | 1S/5K.2H2O5S.2H2O4S/c;;;; |
InChI key | HJKYXKSLRZKNSI-UHFFFAOYSA |
pH | 2.1 (77 °C, 30 g/L) |
Quality Level | 200 |
reaction suitability | reagent type: oxidant |
SMILES string | [K+].[K+].[K+].[K+].[K+]. |
vapor pressure | <0.0000017 hPa |
Application: | A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported. Also used to study fading of an artist′s colorants. |
Application: | Oxidant used for halogenation of α,β-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation. |
Application: | Oxidant used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation. 2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone A Convenient Halogenation of α,β-Unsaturated Carbonyl Compounds with OXONE® and Hydrohalic Acid (HBr, HCl) |
Application: | OXONE®, monopersulfate compound may be used as an alternative to transition-metal oxidants for the conversion of aldehydes to carboxylic acids or esters. |
General description: | OXONE®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant. |
Legal Information: | OXONE is a registered trademark of E. I. du Pont de Nemours and Company |
Packaging: | 1 kg in poly bottle |
Packaging: | 100 g in poly bottle |
Packaging: | 25 kg in fiber drum |
Packaging: | 5 g in glass bottle |
Packaging: | 5 kg in poly drum |
Symbol | GHS05,GHS07,GHS09 |
Signal word | Danger |
Hazard statements | H302 - H314 - H411 |
Precautionary statements | P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | O,C |
Risk Statements | 8-34-42/43 |
Safety Statements | 17-22-26-36/37/39-45-60 |
RIDADR | UN 3260 8 / PGII |
WGK Germany | WGK 2 |
Flash Point(F) | does not flash |
Flash Point(C) | does not flash |
UNSPSC | 12352300 |