OXONE^®, monopersulfate compound

SIAL/228036

Synonym: Potassium peroxymonosulfate

CAS Number: 70693-62-8
Empirical Formula (Hill Notation): HKO₅S · 0.5HKO₄S · 0.5K₂O₄S
Molecular Weight: 307.38
MDL Number: MFCD00040551
Linear Formula: KHSO₅ · 0.5KHSO₄ · 0.5K₂SO₄
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-228036-5G	5 g	$48.00 1/EA	Add To Favorites
45-228036-100G	100 g	$58.50 1/EA	Add To Favorites
45-228036-1KG	1 kg	$79.30 1/EA	Add To Favorites
45-228036-5KG	5 kg	$301.00 1/EA	Add To Favorites
45-228036-25KG	25 kg	$673.00 1/EA	Add To Favorites

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This image depicts SKU: 228036-100G

Properties
Descriptions
Safety Info.
Basic Data

assay	>4.0% active oxygen basis (by Na₂S₂O₃, titration)
form	powder
InChI	1S/5K.2H2O5S.2H2O4S/c;;;;;21-5-6(2,3)4;21-5(2,3)4/h;;;;;21H,(H,2,3,4);2(H2,1,2,3,4)/q5*+1;;;;/p-5
InChI key	HJKYXKSLRZKNSI-UHFFFAOYSA-I
pH	2.1 (77 °C, 30 g/L)
Quality Level	100
reaction suitability	reagent type: oxidant
SMILES string	[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O
vapor pressure	<0.0000017 hPa

Application:	A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported. Also used to study fading of an artist′s colorants.
Application:	Oxidant used for halogenation of α,β-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.
Application:	Oxidant used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation. 2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone A Convenient Halogenation of α,β-Unsaturated Carbonyl Compounds with OXONE^® and Hydrohalic Acid (HBr, HCl)
Application:	OXONE^®, monopersulfate compound may be used as an alternative to transition-metal oxidants for the conversion of aldehydes to carboxylic acids or esters.
General description:	OXONE^®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.
Legal Information:	OXONE is a registered trademark of E. I. du Pont de Nemours and Company
Packaging:	1 kg in poly bottle
Packaging:	100 g in poly bottle
Packaging:	25 kg in fiber drum
Packaging:	5 g in glass bottle
Packaging:	5 kg in poly drum

Symbol	GHS05,GHS07,GHS09
Signal word	Danger
Hazard statements	H302 - H314 - H411
Precautionary statements	P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	O,C
Risk Statements	8-34-42/43
Safety Statements	17-22-26-36/37/39-45-60
RIDADR	UN 3260 8 / PGII
WGK Germany	WGK 2
Flash Point(F)	does not flash
Flash Point(C)	does not flash

Purity	>4.0% active oxygen basis (by Na₂S₂O₃, titration)
UNSPSC	12352300

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