Citric acid
SIAL/251275 - ACS reagent, ≥99.5%
Synonym: 2-
CAS Number: 77-92-9
Empirical Formula (Hill Notation): C6H8O7
Molecular Weight: 192.12
EC Number: 201-069-1
MDL Number: MFCD00011669
Linear Formula: HOC(COOH)(CH2COOH)2
Product Type: Chemical
| anion traces | chloride (Cl-): ≤0.001% |
| oxalate (C2O42-): passes test (limit about 0.003%) | |
| phosphate (PO43-): ≤0.001% | |
| sulfate (SO42-): ≤0.002% | |
| assay | ≥99.5% |
| cation traces | Fe: ≤3 ppm |
| Pb: ≤2 ppm | |
| expl. lim. | 8 %, 65 °F |
| form | crystals |
| functional group | carboxylic acid |
| hydroxyl | |
| grade | ACS reagent |
| ign. residue | ≤0.02% |
| impurities | Substances carbonizable by hot sulfuric acid, passes test |
| InChI | 1S/C6H8O7/c7-3(8)1-6(13,5 |
| InChI key | KRKNYBCHXYNGOX-UHFFFAOYSA |
| mp | 153-159 °C (lit.) |
| pKa | (1) 3.13, (2) 4.76, (3) 6.4 |
| Quality Level | 200 ![]() |
| SMILES string | OC(=O)CC(O)(CC(O)=O)C(O)= |
| storage temp. | room temp |
| Application: | Citric acid has been used to prepare: • Phosphate citrate buffer for use in enzyme-linked immunosorbent assay. • Citrate-stabilized ceria aqueous sol, which was employed in the synthesis of cerium oxide nanoparticles. • Citric acid-Na2HPO4-buffered stock solution for use in the determination of fecal urease activity. • Anticoagulant citrate dextrose solution A (ACD-A), which is employed during the isolation of blood-derived endothelial progenitor cells. Citric acid has also been used: • In a novel process which allows controlling of the particle size during the synthesis of palladium cuboctahedrons. • To prepare citric acid-derived carbon nanodots (CNDs) by bottom-up carbonization method. • As a bi-component chelating agent for the synthesis of Li4Ti5O12 (lithium titanate oxide) by a novel sol–gel method. |
| General description: | Citric acid is a weak organic acid that is commonly used for pH adjustment, as a chelating agent, as a buffering agent, derivatization and as starting material for the synthesis of citrate esters and other compounds. |
| Legal Information: | Redi-Dri is a trademark of Sigma-Aldrich Co. LLC |
| Other Notes: | Go to Redi-Dri™ Product Listing 791725 ![]() |
| Packaging: | 1, 2.5 kg in poly bottle |
| Packaging: | 12 kg in fiber drum |
| Packaging: | 5, 100, 500 g in poly bottle |
| Symbol | GHS07 |
| Signal word | Warning |
| Hazard statements | H319 |
| Precautionary statements | P264 - P280 - P305 + P351 + P338 - P337 + P313 |
| Hazard Codes | Xi |
| Risk Statements | 36 |
| Safety Statements | 26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 1 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥99.5% |
| mp | 153-159 °C (lit.) |
| Storage Temp. | room temp |
| UNSPSC | 12352100 |


