Anisole
SIAL/296295 - anhydrous, 99.7%
Synonym: Methoxybenzene; Methyl phenyl ether
CAS Number: 100-66-3
Empirical Formula (Hill Notation): C7H8O
Molecular Weight: 108.14
EC Number: 202-876-1
MDL Number: MFCD00008354
Linear Formula: CH3OC6H5
Product Type: Chemical
Anhydrous, Sureseal
Anhydrous, Sureseal
| assay | 99.7% |
| autoignition temp. | 887 °F |
| bp | 154 °C (lit.) |
| density | 0.995 g/mL at 25 °C (lit.) |
| evapn. residue | <0.0003% |
| expl. lim. | 8 % |
| form | liquid |
| grade | anhydrous |
| impurities | <0.002% water |
| <0.005% water (100 mL pkg) | |
| InChI | 1S/C7H8O/c1-8-7-5-3-2-4-6 |
| InChI key | RDOXTESZEPMUJZ-UHFFFAOYSA |
| mp | −37 °C (lit.) |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | COc1ccccc1 |
| vapor density | 3.7 (vs air) |
| vapor pressure | 10 mmHg ( 42.2 °C) |
| Application: | Anisole may undergo: • Zeolite-catalyzed Friedel-Crafts acylation with acetic anhydride in acetic acid to form 4-methoxyacetophenone with high selectivity. • Bismuth triflate-catalyzed Friedel-Crafts benzoylation with benzoic anhydride to form 4-methoxybenzophenone under solvent-free microwave irradiation. It may also be used as a surrogate for lignin primary tar in pyrolysis experiments. |
| Packaging: | 1, 2 L in Sure/Seal™ |
| Packaging: | 100 mL in Sure/Seal™ |
| Symbol |   GHS02,GHS07 |
| Signal word | Warning |
| Hazard statements | H226 - H336 |
| Precautionary statements | P210 - P233 - P240 - P241 - P242 - P243 |
| Risk Statements | 10-66 |
| Safety Statements | 26 |
| RIDADR | UN 2222 3 / PGIII |
| WGK Germany | WGK 2 |
| Flash Point(F) | 125.1 °F - closed cup |
| Flash Point(C) | 51.7 °C - closed cup |
| Supplemental Hazard Statements | EUH066 |
| Purity | 99.7% |
| bp | 154 °C (lit.) |
| mp | −37 °C (lit.) |
| Density | 0.995 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352112 |