Chloramine T trihydrate
SIAL/31224 - reag. Ph. Eur., 98.0-103.0%
Synonym: N-Chloro-p-toluenesulfonamide sodium salt
CAS Number: 7080-50-4
Empirical Formula (Hill Notation): C7H7ClNNaO2S · 3H2O
Molecular Weight: 281.69
EC Number: 204-854-7
MDL Number: MFCD00149066
Linear Formula: CH3C6H4SO2NClNa · 3H2O
Product Type: Chemical
agency | reag. Ph. Eur. |
USP/NF | |
assay | 98.0-103.0% |
impurities | ≤1.5% insoluble in ethanol |
InChI | 1S/C7H7ClNO2S.Na.3H2O/c1- |
InChI key | NZYOAGBNMCVQIV-UHFFFAOYSA |
mp | 167-170 °C (lit.) |
pH | 8-10 (20 °C, 5%) |
Quality Level | 100 |
SMILES string | O.O.O.Cc1ccc(cc1)S(=O)(=O |
Application: | Chloramine-T trihydrate can be used as:• A reagent for chlorination in drinking water treatment. • A dehydrogenating agent for the oxidative dehydrogenation of aromatic aldehyde phenylhydrazones to synthesize nitrile imines. • The nitrene source for the aziridination of alkenes and the amidation of cyclic ethers. |
General description: | Chloramine-T trihydrate is a widely used oxidizing agent in organic synthesis. It acts as a source of halonium cation and nitrogen anion and thus acts as a base and nucleophile. Due to its reactivity with a wide range of functional groups, it is involved in different molecular transformations. It is effective in acidic, neutral, and basic conditions. |
Symbol | GHS05,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H302 - H314 - H334 |
Precautionary statements | P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
Hazard Codes | C |
Risk Statements | 22-31-34-42 |
Safety Statements | 7-22-26-36/37/39-45 |
RIDADR | UN 3263 8 / PGIII |
WGK Germany | WGK 2 |
Flash Point(F) | 377.6 °F - closed cup |
Flash Point(C) | 192 °C - closed cup |
Supplemental Hazard Statements | EUH031 |
Purity | 98.0-103.0% |
mp | 167-170 °C (lit.) |
UNSPSC | 12352100 |