Methyl chloroacetate
SIAL/36546 - PESTANAL®, analytical standard
CAS Number: 96-34-4
Empirical Formula (Hill Notation): C3H5ClO2
Molecular Weight: 108.52
EC Number: 202-501-1
MDL Number: MFCD00000931
Linear Formula: ClCH2COOCH3
Product Type: Chemical
| application(s) | agriculture environmental |
| autoignition temp. | 869 °F |
| bp | 130 °C/740 mmHg (lit.) |
| density | 1.238 g/mL at 25 °C (lit.) |
| expl. lim. | 18.5 % |
| format | neat |
| grade | analytical standard |
| InChI | 1S/C3H5ClO2/c1-6-3(5)2-4/ |
| InChI key | QABLOFMHHSOFRJ-UHFFFAOYSA |
| mp | −33 °C (lit.) |
| product line | PESTANAL® |
| Quality Level | 100  |
| refractive index | n |
| shelf life | limited shelf life, expiry date on the label |
| SMILES string | COC(=O)CCl |
| technique(s) | gas chromatography (GC): suitable |
| HPLC: suitable | |
| vapor density | 3.8 (vs air) |
| vapor pressure | 10 mmHg ( 25 °C) |
| 5.25 mmHg ( 20 °C) |
| Application: | Methyl chloroacetate can find applications as a solvent in the liquid-liquid extraction of neutral compounds like alkylphenones, separated using micellar electrokinetic chromatography. |
| Application: | Methyl chloroacetate can find applications as a solvent in the liquid-liquid extraction of neutral compounds like alkylphenones, separated using micellar electrokinetic chromatography.Methyl chloroacetate may be used as a precursor for the synthesis of d3-labeled dimethoate, an internal standard used for the quantification of dimethoate in food samples using isotope dilution and liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) with multiple reaction monitoring mode (MRM). |
| Application: | Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support. |
| Legal Information: | PESTANAL is a registered trademark of Sigma-Aldrich International GmbH |
| Symbol |    GHS02,GHS05,GHS06 |
| Signal word | Danger |
| Hazard statements | H226 - H301 + H331 - H315 - H318 - H335 |
| Precautionary statements | P210 - P280 - P301 + P310 + P330 - P302 + P352 - P304 + P340 + P311 - P305 + P351 + P338 + P310 |
| Hazard Codes | T |
| Risk Statements | 10-23/25-37/38-41 |
| Safety Statements | 26-37/39-45 |
| RIDADR | UN 2295 3(6.1) / PGI |
| WGK Germany | WGK 3 |
| Flash Point(F) | 116.6 °F - closed cup |
| Flash Point(C) | 47 °C - closed cup |
| bp | 130 °C/740 mmHg (lit.) |
| mp | −33 °C (lit.) |
| Density | 1.238 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 41116107 |