Pentafluoropropionic anhydride

SIAL/394904 - for GC derivatization, LiChropur^™, 99%

Synonym: PFPA; Perfluoropropionic anhydride

CAS Number: 356-42-3
Empirical Formula (Hill Notation): C₆F₁₀O₃
Molecular Weight: 310.05
EC Number: 206-604-2
MDL Number: MFCD00000429
Linear Formula: (CF₃CF₂CO)₂O
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-394904-10X1ML	1 mL	$217.00 10/EA		Add To Favorites
45-394904-5ML	5 mL	$121.00 1/EA		Add To Favorites
45-394904-25ML	25 mL	$292.00 1/EA		Add To Favorites
45-394904-100ML	100 mL	$1100.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	99%
bp	69-70 °C/735 mmHg (lit.)
density	1.571 g/mL at 25 °C (lit.)
form	liquid
grade	for GC derivatization
InChI	1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16
InChI key	XETRHNFRKCNWAJ-UHFFFAOYSA-N
quality	LiChropur^™
Quality Level	100
reaction suitability	reagent type: derivatization reagent reaction type: Acylations
SMILES string	FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F
technique(s)	gas chromatography (GC): suitable

Application:	Learn more in the Product Information
Application:	Derivatization reagent used in a GC-MS analysis of stereoisomer content of synthetic peptides. Also used in a GC-MS detection method for synephrine in dietary supplements.
Application:	For the preparation of volatile pentafluoropropionyl derivatives of a wide range of compounds, for example, amines and alcohols, for EC/GC.
Application:	Pentafluoropropionic anhydride (PFPA) was used as derivatization reagent for urine samples to determine the presence of codeine, morphine, 6-monoacetylmorphine, ethylmorphine, and dihydrocodeine using GC-MS in selected ion monitoring (SIM) mode. It was also used to derivatize the dry pericardial fluid sample extracts for quantification of cocaine, benzoylecgonine, and cocaethylene in pericardial fluid using GC-MS.
Legal Information:	LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
Packaging:	10×1, 5, 25, 100 mL in ampule
Packaging:	Clear borosilicate glass, high hydrolytic resistance (Type I)

Symbol	GHS05
Signal word	Danger
Hazard statements	H314
Precautionary statements	P280 - P305 + P351 + P338 - P310
Hazard Codes	C
Risk Statements	14-34
Safety Statements	26-36/37/39-45
RIDADR	UN 3265 8 / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable
Supplemental Hazard Statements	EUH014

Purity	99%
bp	69-70 °C/735 mmHg (lit.)
Density	1.571 g/mL at 25 °C (lit.)
UNSPSC	12000000

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