Dimethylglyoxime
SIAL/40390 - puriss. p.a., ACS reagent, for the detection of Ni, ≥99.0% (TLC)
Synonym: 2,3-Butanedione dioxime; Diacetyldioxime
CAS Number: 95-45-4
Empirical Formula (Hill Notation): C4H8N2O2
Molecular Weight: 116.12
EC Number: 202-420-1
MDL Number: MFCD00002117
Linear Formula: CH3C(=NOH)C(=NOH)CH3
Product Type: Chemical
| assay | ≥99.0% (TLC) |
| cation traces | Ca: ≤10 mg/kg |
| Cd: ≤5 mg/kg | |
| Co: ≤5 mg/kg | |
| Cr: ≤5 mg/kg | |
| Cu: ≤5 mg/kg | |
| Fe: ≤5 mg/kg | |
| K: ≤50 mg/kg | |
| Mg: ≤5 mg/kg | |
| Mn: ≤5 mg/kg | |
| Na: ≤50 mg/kg | |
| Ni: ≤5 mg/kg | |
| Pb: ≤5 mg/kg | |
| Zn: ≤5 mg/kg | |
| form | solid |
| functional group | amine |
| oxime | |
| grade | ACS reagent |
| puriss. p.a. | |
| ign. residue | ≤0.05% (as SO4) |
| impurities | ≤0.02% insoluble matter in ethanol |
| InChI | 1S/C4H8N2O2/c1-3(5-7)4(2) |
| InChI key | JGUQDUKBUKFFRO-GGWOSOGESA |
| mp | 240-241 °C (lit.) |
| quality | for the detection of Ni |
| Quality Level | 200  |
| SMILES string | CC(=N/O)C(C)=NO |
| solubility | water: soluble 0.1 g/10 mL, clear, colorless |
| technique(s) | UV/Vis spectroscopy: suitable |
| Application: | Dimethylglyoxime (DMG) was used as complexing agent for cobalt(II) and nickel(II) metals for the analysis of brine for trace metals by adsorptive stripping voltammetry. DMG was used in a study to develop a new DMG containing modified sol-gel carbon composite electrode for voltammetric sensing of heavy metals. |
| General description: | Dimethylglyoxime (DMG) is a complexing ligand. Dimethylglyoxime forms a number of mixed ligand complexes with N-acetylglycine with metals such as VO(IV), Ni(II), Zn(II), Pd(II), Cd(II) and Pb(II). It is a useful reagent for the spectrophotometric determination of Co(II), Fe(II), Ni(II), Pd(II) and Re(VII). |
| Symbol |  GHS02 |
| Signal word | Warning |
| Hazard statements | H228 |
| Precautionary statements | P210 - P240 - P241 - P280 - P370 + P378 |
| Hazard Codes | F,T |
| Risk Statements | 11-25 |
| Safety Statements | 45 |
| RIDADR | UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., H |
| WGK Germany | WGK 3 |
| Purity | ≥99.0% (TLC) |
| mp | 240-241 °C (lit.) |
| UNSPSC | 12352100 |