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Hexamethyldisiloxane

SIAL/52630 - puriss., ≥98.5% (GC)

Synonym: HMDSO

CAS Number: 107-46-0
Empirical Formula (Hill Notation): C6H18OSi2
Molecular Weight: 162.38
EC Number: 203-492-7
MDL Number: MFCD00008265
Linear Formula: (CH3)3SiOSi(CH3)3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-52630-100ML 100 mL
$33.50
1/EA
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45-52630-500ML 500 mL
$94.90
1/EA
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45-52630-1L 1 L
$136.00
1/EA
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assay ≥98.5% (GC)
bp 101 °C (lit.)
density 0.764 g/mL at 20 °C (lit.)
form liquid
grade puriss.
InChI 1S/C6H18OSi2/c1-8(2,3)7-9(4,5)6/h1-6H3
InChI key UQEAIHBTYFGYIE-UHFFFAOYSA-N
mp −59 °C (lit.)
Quality Level 200 
refractive index n20/D 1.377
  n20/D 1.377 (lit.)
SMILES string C[Si](C)(C)O[Si](C)(C)C
vapor density >1 (vs air)
Application: Hexamethyldisiloxane is used:• As a modifying agent in the presence of ethanol/n-hexane solution for the preparation of hydrophobic and hydrophilic sodium silicate-based silica xerogels.
• To form the dielectric layers in the MIM(metal-insulator-metal) structure that is consisting of graphene quantum dots(GQDs) to prepare two-terminal NVM (non-volatile-memory) devices.
Features and Benefits: Hexamethyldisiloxanehas high thermal stability.
General description: HMDSO(hexamethyldisiloxane) is an organosilicon compound. It is a non-toxic, environmentally friendly monomer. It can be used as a precursor to synthesize organosilicon thin films. It serves as a silylating agent for carboxylic acids and alcohols. Additionally, it is used in the preparation of aroyl chlorides. HMDSO is commonly used as a water-repellent.
Other Notes: For a facile silylation of carboxylic acids; As chloride anion acceptor in the synthesis of sulphinic esters
Symbol GHS02GHS09  GHS02,GHS09
Signal word Danger
Hazard statements H225 - H410
Precautionary statements P210 - P273
Hazard Codes F,N
Risk Statements 11-50/53
Safety Statements 16-61
RIDADR UN1993 - class 3 - PG 2 - EHS - VP <= 110kPa - Flammable liquids
WGK Germany WGK 2
Flash Point(F) 21.2 °F - closed cup
Flash Point(C) -6 °C - closed cup
Purity ≥98.5% (GC)
bp 101 °C (lit.)
mp −59 °C (lit.)
Density 0.764 g/mL at 20 °C (lit.)
Refractive Index n20/D 1.377 (lit.); n20/D 1.377
UNSPSC 12352103

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