Tetramethylammonium chloride

SIAL/74202 - suitable for ion pair chromatography, LiChropur^™, ≥99.0% (AT)

Synonym: TMA

CAS Number: 75-57-0
Empirical Formula (Hill Notation): C₄H₁₂ClN
Molecular Weight: 109.60
EC Number: 200-880-8
MDL Number: MFCD00011628
Linear Formula: (CH₃)₄N(Cl)
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-74202-50G-F	50 g	$90.70 1/EA		Add To Favorites
45-74202-250G-F	250 g	$361.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

λ	10 % in H₂O
assay	≥99.0% (AT)
description	cationic
form	crystals
InChI	1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI key	OKIZCWYLBDKLSU-UHFFFAOYSA-M
mp	>300 °C (lit.)
quality	LiChropur^™
Quality Level	100
SMILES string	[Cl-].C[N+](C)(C)C
suitability	corresponds to standard for filter test
	corresponds to standard for RP gradient test
technique(s)	ion pair chromatography: suitable
UV absorption	λ: 220 nm A_max: 0.05
	λ: 230 nm A_max: 0.04
	λ: 250 nm A_max: 0.03
	λ: 260 nm A_max: 0.02
	λ: 500 nm A_max: 0.02

Application:	TMAC may be used in ion-exchange procedures to show the increase of pH in understanding the chemical behaviour of catalyst [CTA]Si-MCM-41 using Knoevenagel condensation model.
General description:	Tetramethylammonium chloride (TMAC) is structurally similar to alkyltrimethylammonium salts. Oxidation of TMAC yields formaldehyde and trimethlamine. It is considered as poor phase-transfer catalyst for most reactions as it is insoluble in organic media. However, it is highly suitable as phase-transfer catalyst for fluorination of chlorobenzaldehydes along with alkali metal fluorides which yield 1,2,2,2-tetrafluoroethyldifluoromethyl ether.
Legal Information:	LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Symbol	GHS06,GHS08,GHS09
Signal word	Danger
Hazard statements	H300 - H311 - H315 - H370 - H411
Precautionary statements	P260 - P264 - P273 - P280 - P301 + P310 - P302 + P352 + P312
Hazard Codes	T,N
Risk Statements	24/25-38-39/25-51/53
Safety Statements	28-35-36/37-45-46-61
RIDADR	UN 2811 6.1 / PGII
WGK Germany	WGK 1

Purity	≥99.0% (AT)
mp	>300 °C (lit.)
UNSPSC	23151817

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