(R)-(+)-α-Methylbenzylamine

SIAL/77879 - for chiral derivatization, LiChropur^™, ≥99.0%

Synonym: (R)-(+)-1-Phenylethylamine

CAS Number: 3886-69-9
Empirical Formula (Hill Notation): C₈H₁₁N
Molecular Weight: 121.18
EC Number: 223-423-4
MDL Number: MFCD00064405
Linear Formula: C₆H₅CH(CH₃)NH₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-77879-5ML	5 mL	$0.00 1/EA CALL FOR PRICE		Add To Favorites
45-77879-25ML	25 mL	$467.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	≥99.0%
	≥99.0% (sum of enantiomers, GC)
bp	187-189 °C (lit.)
density	0.952 g/mL at 20 °C (lit.)
form	liquid
grade	for chiral derivatization
InChI	1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1
InChI key	RQEUFEKYXDPUSK-SSDOTTSWSA-N
optical activity	[α]20/D +30±1°, c = 10% in ethanol
optical purity	enantiomeric ratio: ≥99.5:0.5 (GC)
quality	LiChropur^™
Quality Level	100
refractive index	n20/D 1.526 (lit.)
	n20/D 1.528
SMILES string	C[C@@H](N)c1ccccc1
storage temp.	2-8°C
technique(s)	HPLC: suitable
vapor pressure	0.5 mmHg ( 20 °C)

Application:	(R)-(+)-a-Methylbenzylamine also known as (R)-(+)-1-Phenylethylamine may be used in resolution of a chiral arylalkylamine involving high-conversion enantioselective condensation with capric acid followed by hydrolysis to yield corresponding (R)-(+)-amide.
General description:	(R)-(+)-α-Methylbenzylamine is a high quality, useful chiral derivatization reagent for all analytical applications, specific to GC in the chiral field. It is specially selected to meet the requirements for derivatization reagents for enantiomeric excess determinations.
Legal Information:	LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
Other Notes:	Chiral amine used for the determination of the enantiomeric purity of acids
Recommended products:	Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Symbol	GHS05,GHS07
Signal word	Danger
Hazard statements	H302 + H312 - H314
Precautionary statements	P280 - P301 + P312 + P330 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	C
Risk Statements	21/22-34
Safety Statements	26-28-36/37/39-45
RIDADR	UN 2735PSN1 8 / PGII
WGK Germany	WGK 3
Flash Point(F)	158.0 °F - closed cup
Flash Point(C)	70 °C - closed cup

Purity	≥99.0% (sum of enantiomers, GC); ≥99.0%
bp	187-189 °C (lit.)
Density	0.952 g/mL at 20 °C (lit.)
Refractive Index	n20/D 1.526 (lit.); n20/D 1.528
Storage Temp.	2-8°C
UNSPSC	12000000

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