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Silver trifluoromethanesulfonate

SIAL/85325 - purum, ≥98.0% (Ag)

Synonym: Ag(OTf); Silver (trifluoromethyl)sulfonate; Silver triflate; Trifluoromethanesulfonic acid silver salt

CAS Number: 2923-28-6
Empirical Formula (Hill Notation): CAgF3O3S
Molecular Weight: 256.94
EC Number: 220-882-2
MDL Number: MFCD00013226
Linear Formula: CF3SO3Ag
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-85325-5G 5 g
$79.10
1/EA
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45-85325-25G 25 g
$189.00
1/EA
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assay ≥98.0% (Ag)
form crystals
grade purum
InChI 1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChI key QRUBYZBWAOOHSV-UHFFFAOYSA-M
Quality Level 100 
reaction suitability core: silver
  reagent type: catalyst
SMILES string [Ag+].[O-]S(=O)(=O)C(F)(F)F
Application: Silver trifluoromethanesulfonate (AgOTf) may be employed as a reagent during glucosylation of several alcohols. AgOTf in combination with p-nitrobenzenesulfenyl chloride may be employed as an activator for the glycosylation.
It may be used for the synthesis of the following:
• cystine-containing peptides
• 3-aminoalkylated indoles
• benzo[b]oxepines and 2H-chromenes
• diversely substituted iminoimidazoazines
General description: Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.
Other Notes: Reagent for the substitution of halides by triflate.; Reagent for the glycosylation of glycosyl halides; Reagent used for the deprotection of protected thiols
Purity ≥98.0% (Ag)
UNSPSC 12352300

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