Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
SIAL/902217 - ≥95%
Synonym: Ir photocatalyst; Photocatalyst
CAS Number: 2030437-92-2
Empirical Formula (Hill Notation): C34H16F18IrN4P
Molecular Weight: 1045.68
Linear Formula: C34H16F18IrN4P
Product Type: Chemical
assay | ≥95% |
form | powder or crystals |
mp | >300 °C |
photocatalyst activation | 450 nm |
reaction suitability | core: iridium |
reagent type: catalyst reaction type: Photocatalysis |
Application: | Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroaren![]() |
Other Notes: | A radical approach to the copper oxidative addition problem:Trifluoromethylat![]() ![]() Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer ![]() ![]() |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥95% |
mp | >300 °C |
UNSPSC | 12352300 |