Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6
SIAL/902225 - ≥95%
Synonym: Photocatalyst
Empirical Formula (Hill Notation): C36H22F16IrN4P
Molecular Weight: 1037.75
Linear Formula: C36H22F16IrN4P
Product Type: Chemical
| assay | ≥95% |
| form | powder |
| mp | >300 °C |
| reaction suitability | core: iridium |
| reagent type: catalyst |
| Application: | Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroaren ) and supersilanol (902489). |
| Other Notes: | A radical approach to the copper oxidative addition problem:Trifluoromethylat |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥95% |
| mp | >300 °C |
| UNSPSC | 41141700 |