Tris(trimethylsilyl)silanol
SIAL/902489 - ≥95%
Synonym: (Hydroxy-
CAS Number: 7428-60-6
Empirical Formula (Hill Notation): C9H28OSi4
Molecular Weight: 264.66
MDL Number: MFCD00093727
Linear Formula: C9H28OSi4
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 902489-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 902489-5G
| assay | ≥95% |
| density | 0.859 g/mL |
| form | liquid |
| refractive index | n |
| Application: | Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroaren ) and Ir photocatalyst (902217 or 902225 ). |
| Other Notes: | A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes  |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | 200.3 °F |
| Flash Point(C) | 93.5 °C |
| Purity | ≥95% |
| Density | 0.859 g/mL |
| Refractive Index | n |
| UNSPSC | 12161700 |