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Chiralyst Rh660

SIAL/908800 - Umicore

Synonym: 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R,R)-Et-DUPHOS-Rh; [(R,R)Ethyl-DuPhosRh(COD)]BF4

CAS Number: 228121-39-9
Empirical Formula (Hill Notation): C30H48BF4P2Rh
Molecular Weight: 660.36
Linear Formula: C30H48BF4P2Rh
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-908800-1G 1 g
 $478.00
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form powder
InChI 1S/C22H36P2.C8H12.BF4.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m1.../s1
InChI key DSYBEQKPSKLNMC-KYOOHHHUSA-N
SMILES string C[CH+]C.CC[C@@H]1CC[C@@H](CC)P12C3=C(P4([Rh](C)2C)[C@H](CC)CC[C@H]4CC)C=CC=C3.FB(F)F.C5C/C=CCC/C=C5.[F-]
Application: DuPhos and BPE Ligands: Highly Efficient Privileged Ligands 

Catalyst for:
• Asymmetric hydrogenation reactions
Application: Chiralyst Rh660 is a homogeneous catalyst useful for asymmetric reactions and asymmetric hydrogenation. The catalyst works well with privileged ligands.
Legal Information: Product of Umicore

Additional information available at www.pmc.umicore.com 
Storage and Stability: Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable

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