Tris(dibenzylideneacetone)dipalladium(0) ChemBeads
SIAL/919772
Synonym: Pd2dba3; Pd2(dba)3
CAS Number: 51364-51-3
Empirical Formula (Hill Notation): C51H42O3Pd2
Molecular Weight: 915.72
MDL Number: MFCD00013310
Linear Formula: (C6H5CH=CHCOCH=CHC6H5)3Pd2
Product Type: Chemical
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| composition | ~ 5 wt.% loading of catalyst |
| form | solid |
| InChI key | CYPYTURSJDMMMP-WVCUSYJESA |
| Quality Level | 100  |
| SMILES string | O=C(/C=C/c1ccccc1)/C=C/c2 |
| storage temp. | 2-8°C |
| Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions Reactant involved in: • Synthesis of nanosized palladium phosphides upon interaction with white phosphorous • Preparation of palladium triphenylphosphine carbonyl cluster complexes • Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions • Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes Catalyst for: • Suzuki cross-coupling reactions • PCN- and PCS-pincer palladium complex catalyzed tandem allylation |
| Application: | Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis Catalyst for C-C and C-N bond formation especially Suzuki, Heck coupling reaction ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical. |
| Legal Information: | Tris(dibenzylideneacetone Additional information available at www.pmc.umicore.com  |
| Other Notes: | High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand |
| Symbol |   GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H317 - H350i - H412 |
| Precautionary statements | P201 - P202 - P273 - P280 - P302 + P352 - P308 + P313 |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Storage Temp. | 2-8°C |