[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads
SIAL/919780
Synonym: Pd(dppf)Cl2
CAS Number: 72287-26-4
Linear Formula: (C17H14P)2Fe . PdCl2
Product Type: Chemical
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| composition | ~ 4 wt.% loading of catalyst |
| form | solid |
| Quality Level | 100  |
| Application: | Catalyst for C-C and C-N coupling reaction. Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions: • Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity. • Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives. • Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes. ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical. |
| Other Notes: | High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads  Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand |
| Symbol |  GHS08 |
| Signal word | Danger |
| Hazard statements | H350i |
| Precautionary statements | P201 - P202 - P280 - P308 + P313 - P405 - P501 |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |