Palladium(II) chloride ChemBeads
SIAL/919853
CAS Number: 7647-10-1
Empirical Formula (Hill Notation): Cl2Pd
Molecular Weight: 177.33
MDL Number: MFCD00003558
Linear Formula: Cl2Pd
Product Type: Chemical
composition | ~ 4 wt.% loading of catalyst |
form | solid |
InChI | 1S/2ClH.Pd/h2*1H;/q;;+2/p |
InChI key | PIBWKRNGBLPSSY-UHFFFAOYSA |
Quality Level | 100 ![]() |
SMILES string | Cl[Pd]Cl |
Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions ![]() Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar. |
Application: | Palladium(II) chloride (PdCl2) was used in the following studies: • As catalyst for the carbonylation of organic tellurides by reaction with carbon monoxide. • As a catalyst along with Cu(II) for the deamination of phenethylamines to phenyl substituted pyrroles. • Together with PEG 300, promoted efficient Suzuki-coupling of aryl chlorides with aryl boronic acids. ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical. |
General description: | Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy |
Other Notes: | High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads ![]() ![]() Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation ![]() ![]() ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand ![]() ![]() |
Symbol | ![]() ![]() ![]() ![]() |
Signal word | Danger |
Hazard statements | H290 - H317 - H318 - H350i - H410 |
Precautionary statements | P201 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313 |
WGK Germany | WGK 3 |