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Palladium(II) chloride ChemBeads

SIAL/919853

CAS Number: 7647-10-1
Empirical Formula (Hill Notation): Cl2Pd
Molecular Weight: 177.33
MDL Number: MFCD00003558
Linear Formula: Cl2Pd
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-919853-250MG 250 mg
$124.00
1/EA
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45-919853-1G 1 g
$311.00
1/EA
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composition ~ 4 wt.% loading of catalyst
form solid
InChI 1S/2ClH.Pd/h2*1H;/q;;+2/p-2
InChI key PIBWKRNGBLPSSY-UHFFFAOYSA-L
Quality Level 100 
SMILES string Cl[Pd]Cl
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
Application: Palladium(II) chloride (PdCl2) was used in the following studies:
• As catalyst for the carbonylation of organic tellurides by reaction with carbon monoxide.
• As a catalyst along with Cu(II) for the deamination of phenethylamines to phenyl substituted pyrroles.
• Together with PEG 300, promoted efficient Suzuki-coupling of aryl chlorides with aryl boronic acids.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
General description: Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF4] or [bmim][PF6] (where[bmim]+ = 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.
Other Notes: High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads 

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation 

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand 

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