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Levoglucosenone

SIAL/923133 - ≥95%

Synonym: (-)-Levoglucosenone; LGO; (1S,5R)-6,8-dioxabicyclo[3.2.1]oct-2-en-4-one; 1,6-anhydro-3,4-dideoxyhex-3-enopyran-2-ulose; 6,8-Dioxabicyclo[3.2.1]oct-2-en-4-one

CAS Number: 37112-31-5
Empirical Formula (Hill Notation): C6H6O3
Molecular Weight: 126.11
MDL Number: MFCD00191664
Linear Formula: C6H6O3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-923133-100G
$528.00
1/EA
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12 Principles of Green Chemistry: Principle 5—Safer Solvents and Auxiliaries. This product utilizes reduced volumes of auxiliary substances that are less hazardous.
12 Principles of Green Chemistry: Principle 7—A raw material or feedstock should be renewable rather than depleting whenever technically and economically practicable.

 

assay ≥95%
density 1.32 g/mL
form liquid
greener alternative category Aligned 
greener alternative product characteristics Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry .
InChI 1S/C6H6O3/c7-5-2-1-4-3-8-6(5)9-4/h1-2,4,6H,3H2/t4-,6+/m0/s1
InChI key HITOXZPZGPXYHY-UJURSFKZSA-N
Quality Level 100 
refractive index n/D 1.50625
SMILES string [H][C@]1(C=CC2=O)CO[C@]2([H])O1
storage temp. 2-8°C
Application: Levoglucosenone may be used in the synthesis of the following:
• Various deoxy, keto and branched-chain sugars
• 4-thio and 4-substituted sugar derivatives
• Natural stereoisomer of serricornin
General description: We are committed to bringing you greener alternative products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is biorenewable and thus aligns with ″Safer Solvents and Auxiliaries″ and ″Use of Renewable Feedstocks″. Click here  for more information.
Levoglucosenone undergoes Michael-addition reaction with diethyl malonate, ethyl cyanoacetate, 2-nitropropane and 2-methylcyclohexanone in the presence of various catalysts to afford 4-substituted levoglucosenone derivatives having the D-erythro configuration.
Other Notes: Levoglucosenone: A Chiral Platform Molecule Produced from Biomass 
Purity ≥95%
Density 1.32 g/mL
Refractive Index n/D 1.50625
Storage Temp. 2-8°C

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