Dimethyl carbonate
SIAL/D152927 - ReagentPlus®, 99%
Synonym: Carbonic acid dimethyl ester
CAS Number: 616-38-6
Empirical Formula (Hill Notation): C3H6O3
Molecular Weight: 90.08
EC Number: 210-478-4
MDL Number: MFCD00008420
Linear Formula: (CH3O)2CO
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: D152927-500G.
12 Principles of Green Chemistry: Principle 3—Less Hazardous Chemical Syntheses. This product manufacturing process was designed with lesser toxicity to human health and the environment.
12 Principles of Green Chemistry: Principle 5—Safer Solvents and Auxiliaries. This product utilizes reduced volumes of auxiliary substances that are less hazardous.
12 Principles of Green Chemistry: Principle 10—Chemical products should be designed so that at the end of their function they break down into innocuous degradation products and do not persist in the environment.
| assay | 99% |
| bp | 90 °C (lit.) |
| density | 1.069 g/mL at 25 °C (lit.) |
| dilution | (for general lab use) |
| form | liquid |
| greener alternative category |  , Aligned |
| greener alternative product characteristics | Less Hazardous Chemical Syntheses Safer Solvents and Auxiliaries Design for Degradation Learn more about the Principles of Green Chemistry . |
| InChI | 1S/C3H6O3/c1-5-3(4)6-2/h1 |
| InChI key | IEJIGPNLZYLLBP-UHFFFAOYSA |
| mp | 2-4 °C (lit.) |
| product line | ReagentPlus® |
| Quality Level | 200 |
| refractive index | n |
| SMILES string | O=C(OC)OC |
| sustainability | Greener Alternative Product |
| vapor density | 3.1 (vs air) |
| vapor pressure | 18 mmHg ( 21.1 °C) |
| Application: | Dimethyl carbonate may be used to synthesize: • Methyl phenyl carbonate by transesterification with phenol. • Diphenyl carbonate by transesterification with methyl phenyl carbonate. • Methyl carbamates, a raw material for isocyanate synthesis. • Tetramethoxysilane by reacting with silica at 550-600K. |
| Features and Benefits: | Greener solvent |
| General description: | Dimethyl carbonate (DMC) is a versatile, non-toxic, biodegradable reagent with tunable chemical reactivity. It serves as a green alternative to dimethyl sulfate or methyl halides and phosgene for methylation and carboxylation reactions. The base-catalyzed reaction between carbon dioxide and methanol to form DMC has been studied. Various thermodynamic parameters of DMC have been reported. We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is a Greener alternative to conventional solvents and chemicals. Click here  for more information. |
| Legal Information: | ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany |
| Packaging: | 1 L in glass bottle |
| Packaging: | 100, 500 g in glass bottle |
| Packaging: | 19 kg in VerSA-Flow™ |
| Packaging: | 2.5 kg in glass bottle |
| Packaging: | 500 mL in glass bottle |
| Symbol |  GHS02 |
| Signal word | Danger |
| Hazard statements | H225 |
| Precautionary statements | P210 - P403 + P235 |
| Hazard Codes | F |
| Risk Statements | 11 |
| Safety Statements | 9-16 |
| RIDADR | UN1161 - class 3 - PG 2 - Dimethyl carbonate |
| WGK Germany | WGK 1 |
| Flash Point(F) | 60.8 °F - closed cup |
| Flash Point(C) | 16 °C - closed cup |
| Purity | 99% |
| bp | 90 °C (lit.) |
| mp | 2-4 °C (lit.) |
| Density | 1.069 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |