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2,6-Lutidine

SIAL/L3900 - ReagentPlus®, 98%

Synonym: 2,6-Dimethylpyridine

CAS Number: 108-48-5
Empirical Formula (Hill Notation): C7H9N
Molecular Weight: 107.15
EC Number: 203-587-3
MDL Number: MFCD00006345
Linear Formula: C7H9N
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-L3900-100ML-A 100 mL
 $0.00
1/EA
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45-L3900-500ML-A 500 mL
 $0.00
1/EA
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45-L3900-2L-A 2 L
 $0.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: L3900-500ML-A.

 

assay 98%
bp 143-145 °C ((lit.))
  143-145 °C (lit.)
density 0.92  g/mL at 25 °C ((lit.))
  0.92 g/mL at 25 °C (lit.)
form liquid
InChI 1S/C16H27NO4/c1-2-3-4-5-6-7-8-9-10-11-16(20)21-17-14(18)12-13-15(17)19/h2-13H2,1H3
  1S/C7H9N/c1-6-4-3-5-7(2)8-6/h3-5H,1-2H3
InChI key LRKGVVJOUNKTGG-UHFFFAOYSA-N
  OISVCGZHLKNMSJ-UHFFFAOYSA-N
mp −6 °C (lit.)
  -6 °C
product line ReagentPlus®
Quality Level 200 
refractive index n20/D 1.497 (lit.)
SMILES string Cc1cccc(C)n1
  CCCCCCCCCCCC(=O)ON1C(=O)CCC1=O
Application: 2,6-Lutidine can be used as a base for the oxidation of α-CF3 alcohols to the corresponding carbonyl compounds in the presence of 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (Bobbitt′s salt) as oxidation reagent.
It can be used:
• As a promoter for catalytic asymmetric fluorination of α-cyanophosphonates in the presence of chiral Pd(II)-bisphosphine complexes.
• In combination with tert-butyldimethylsilyl triflate for the protection of tertiary alcohols and unreactive secondary alcohols.
• In combination with triethylsilyl trifluoromethanesulfonate for the conversion of acetals to the corresponding aldehydes in dichloromethane followed by workup in water.
Legal Information: ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Packaging: 100, 500 mL in glass bottle
Packaging: 2 L in glass bottle
Purity 98%
bp 143-145 °C ((lit.)); 143-145 °C (lit.)
mp -6 °C; −6 °C (lit.)
Density 0.92  g/mL at 25 °C ((lit.)); 0.92 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.497 (lit.)
UNSPSC 12352005

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