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Potassium hexacyanocobaltate(III)

SIGALD/12902 - ≥97.0%

Synonym: Tripotassium hexacyanocobaltate(III)

CAS Number: 13963-58-1
Empirical Formula (Hill Notation): C6CoK3N6
Molecular Weight: 332.33
EC Number: 237-742-1
MDL Number: MFCD00011391
Linear Formula: K3Co(CN)6
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-12902-250G-R 250 g
$272.00
1/EA
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This image depicts SKU: 12902-250G-R

 

anion traces sulfate (SO42-): ≤500 mg/kg
assay ≥97.0%
cation traces Fe: ≤50 mg/kg
density 1.878 g/mL at 25 °C (lit.)
form crystalline
impurities ≤0.1% free cyanide
InChI 1S/6CN.Co.3K/c6*1-2;;;;/q;;;;;;-3;3*+1
InChI key VSUFNKULKBVQQW-UHFFFAOYSA-N
Quality Level 100 
reaction suitability reagent type: catalyst
core: cobalt
SMILES string [K+].[K+].[K+].N#C[Co-3](C#N)(C#N)(C#N)(C#N)C#N
suitability suitable for acidity or alkalinity (alkalinity <= 0.15 meq/g)
Application: Potassiumhexacyanocobaltate(III) can be used as a complexing agent to synthesize double metal cyanide catalyst:• For the chemoselective reductive amination of carbonyl compounds with aromatic amines to synthesize substituted amines in the presence of polymethylhydrosiloxane as a reducing agent.
• In the ring opening polymerization of propylene oxide to synthesize polyols.
• In the coupling reaction of CO2 with hydrous epoxides to synthesize cyclic carbonates.
Packaging: 250 g in poly bottle
Hazard Codes Xn
Risk Statements 22
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥97.0%
Density 1.878 g/mL at 25 °C (lit.)
UNSPSC 12352300

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