Potassium hexacyanocobaltate(III)

SIGALD/12902 - ≥97.0%

Synonym: Tripotassium hexacyanocobaltate(III)

CAS Number: 13963-58-1
Empirical Formula (Hill Notation): C₆CoK₃N₆
Molecular Weight: 332.33
EC Number: 237-742-1
MDL Number: MFCD00011391
Linear Formula: K₃Co(CN)₆
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-12902-250G-R	250 g	$286.00 1/EA	Add To Favorites

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This image depicts SKU: 12902-250G-R

Properties
Descriptions
Safety Info.
Basic Data

anion traces	sulfate (SO₄^2-): ≤500 mg/kg
assay	≥97.0%
cation traces	Fe: ≤50 mg/kg
density	1.878 g/mL at 25 °C (lit.)
form	crystalline
impurities	≤0.1% free cyanide
InChI	1S/6CN.Co.3K/c61-2;;;;/q;;;;;;-3;3+1
InChI key	VSUFNKULKBVQQW-UHFFFAOYSA-N
Quality Level	100
reaction suitability	reagent type: catalyst core: cobalt
SMILES string	[K+].[K+].[K+].N#C[Co-3](C#N)(C#N)(C#N)(C#N)C#N
suitability	suitable for acidity or alkalinity (alkalinity <= 0.15 meq/g)

Application:

Potassiumhexacyanocobaltate(III) can be used as a complexing agent to synthesize double metal cyanide catalyst:• For the chemoselective reductive amination of carbonyl compounds with aromatic amines to synthesize substituted amines in the presence of polymethylhydrosiloxane as a reducing agent.
• In the ring opening polymerization of propylene oxide to synthesize polyols.
• In the coupling reaction of CO₂ with hydrous epoxides to synthesize cyclic carbonates.

Packaging:

250 g in poly bottle

Hazard Codes	Xn
Risk Statements	22
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥97.0%
Density	1.878 g/mL at 25 °C (lit.)
UNSPSC	12352202

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