Mercury(II) bromide

SIGALD/200085 - ACS reagent

Synonym: Mercuric bromide

CAS Number: 7789-47-1
Empirical Formula (Hill Notation): Br₂Hg
Molecular Weight: 360.40
EC Number: 232-169-3
MDL Number: MFCD00011040
Linear Formula: HgBr₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-200085-100G	100 g	$268.00 1/EA	Add To Favorites

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This image depicts SKU: 200085-100G

Properties
Descriptions
Safety Info.
Basic Data

anion traces	chloride (Cl^-): ≤0.25%
bp	322 °C (lit.)
color	white to very faintly yellow
form	powder
grade	ACS reagent
impurities	≤0.05% insol. CH₃OH
InChI	1S/2BrH.Hg/h2*1H;/q;;+2/p-2
InChI key	NGYIMTKLQULBOO-UHFFFAOYSA-L
mp	236 °C (lit.)
Quality Level	200
reaction suitability	reagent type: catalyst core: mercury
reduction residue	≤0.02%
SMILES string	Br[Hg]Br
vapor pressure	1 mmHg ( 136.5 °C)

Application:	Mercury(II) bromide (HgBr₂) may be used in the preparation of mononuclear [Hg(L1)Br₂] and 1D polymer [Hg₂(L2)Br₄]_n [L1 = (N,N-diethyl,N′-(pyridin-2-yl)formylidene)ethane-1,2-diamine and L2 = (N,N-diethyl,N′-(pyridin-2-yl)benzylidene)ethane-1,2-diamine]. It may also be used as a promoter in the glycoslyation reaction of alcohols.
General description:	Mercury(II) bromide (HgBr₂) affords 1:1 adducts on reaction with N,N,N′,N′- tetramethyl-o-phenylenediamine. Single-crystal X-ray diffraction studies of these adducts have been reported. It forms complexes by reacting with 3,12-dimethylbenzo[a]quinoxalino[2,3-c]phenazine ligand.
Packaging:	100 g in poly bottle

Symbol	GHS06,GHS08,GHS09
Signal word	Danger
Hazard statements	H300 + H310 + H330 - H373 - H410
Precautionary statements	P262 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310 - P314
Hazard Codes	T+,N
Risk Statements	26/27/28-33-50/53
Safety Statements	13-28-45-60-61
RIDADR	UN 1634 6.1 / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

bp	322 °C (lit.)
mp	236 °C (lit.)
UNSPSC	12352300

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