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Lithium perchlorate

SIGALD/205281 - ACS reagent, ≥95.0%

CAS Number: 7791-03-9
Empirical Formula (Hill Notation): ClLiO4
Molecular Weight: 106.39
EC Number: 232-237-2
MDL Number: MFCD00011079
Linear Formula: LiClO4
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-205281-5G 5 g
 $57.80
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45-205281-100G 100 g
 $123.00
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45-205281-500G 500 g
 $293.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 205281-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205281-5G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 205281-500G

 

anion traces chloride (Cl-): ≤0.003%
  sulfate (SO42-): ≤0.001%
assay ≥95.0%
cation traces Fe: ≤5 ppm
  heavy metals: ≤5 ppm (by ICP-OES)
form powder, chunks or granules
grade ACS reagent
impurities ≤0.005% insolubles
InChI 1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI key MHCFAGZWMAWTNR-UHFFFAOYSA-M
mp 236 °C (lit.)
pH 6.0-7.5 (25 °C, 5%)
Quality Level 200 
reaction suitability reagent type: oxidant
SMILES string [Li+].[O-]Cl(=O)(=O)=O
Application: Lithium perchlorate (LiClO4) may be used as a catalyst in the synthesis of bis(indolyl)methanes.
Application: Lithium perchlorate may be used to catalyze:
• The acylation of hindered alcohols and phenols under solvent-free conditions.
• 1,4-Conjugate addition of O-silylated ketene acetals to hindered αβ,-unsaturated carbonyl system.
• The protection of amine groups as N-Boc derivatives via tert-butoxycarbonylation.
• Synthesis of α-aminophosphonates under solvent free conditions.
Application: When used as a co-catalyst, accelerates the Baylis-Hillman reaction, the coupling of α,β-unsaturated carbonyls with aldehydes.
General description: Lithium perchlorate (LiClO4) is a colorless lithium salt. On the crystallization from its aqueous solution, it affords lithium perchlorate trihydrate (LiClO4.3H2O). It can be synthesized by reacting lithium chloride with perchloric acid.
Packaging: 100, 500 g in poly bottle
Packaging: 5 g in glass bottle
Purity ≥95.0%
mp 236 °C (lit.)
UNSPSC 12352302

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