Potassium thiocyanate
SIGALD/207799 - ACS reagent, 99%
Synonym: Potassium rhodanide
CAS Number: 333-20-0
Empirical Formula (Hill Notation): CKNS
Molecular Weight: 97.18
EC Number: 206-370-1
MDL Number: MFCD00011413
Linear Formula: KSCN
Product Type: Chemical
anion traces | chloride (Cl-): ≤0.005% |
sulfate (SO42-): ≤0.005% | |
assay | 99% |
cation traces | Fe: ≤2 ppm |
heavy metals (as Pb): ≤5 ppm | |
Na: ≤0.005% | |
NH4+: ≤0.003% | |
color | colorless to white |
form | crystalline powder |
grade | ACS reagent |
impurities | Iodine consuming substances, passes test |
≤0.005% insol. water | |
InChI | 1S/CHNS.K/c2-1-3;/h3H;/q; |
InChI key | ZNNZYHKDIALBAK-UHFFFAOYSA |
mp | 173 °C (lit.) |
pH | 5.3-8.7 (25 °C, 5%) |
Quality Level | 200 |
SMILES string | [K]SC#N |
Application: | Potassium thiocyanate (KSCN) may be used for the colorimetric quantification of intracellular iron content of the superparamagnetic iron oxide (SPIO) nanoparticles. |
Application: | Potassium thiocyanate may be used in the synthesis of the following: • α-Amino nitriles from tertiary amines. • Polysubstituted 2-aminothiazoles from vinyl azides. • Benzisothiazol-3(2H)-one derivatives from o-bromobenzamides. • Diaryl thioethers from aryl halides. |
General description: | Potassium thiocyanate is an inorganic potassium salt. Phase transitions in potassium thiocyanate (KSCN) have been investigated by X-ray diffraction studies. The order-disorder type transition with respect to the orientation of the thiocyanate ions was identified. Its polarized infrared spectrum has been reported. It participates in the ring-opening of aziridines. The reaction was carried out in the presence of sulfated zirconia to afford the corresponding β-aminothiocyanates. |
Packaging: | 100, 500 g in poly bottle |
Packaging: | 2.5 kg in poly bottle |
Symbol | GHS05,GHS07 |
Signal word | Danger |
Hazard statements | H302 + H312 + H332 - H318 - H412 |
Precautionary statements | P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 |
Hazard Codes | Xn |
Risk Statements | 20/21/22-32-52/53 |
Safety Statements | 13-36/37-46-61 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 1 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Supplemental Hazard Statements | EUH032 |
Purity | 99% |
mp | 173 °C (lit.) |
UNSPSC | 12352300 |