Tin(II) chloride
SIGALD/208256 - reagent grade, 98%
Synonym: Stannous chloride
CAS Number: 7772-99-8
Empirical Formula (Hill Notation): Cl2Sn
Molecular Weight: 189.62
EC Number: 231-868-0
MDL Number: MFCD00011241
Linear Formula: SnCl2
Product Type: Chemical
assay | 98% |
bp | 652 °C (lit.) |
form | crystalline |
powder or flakes | |
grade | reagent grade |
InChI | 1S/2ClH.Sn/h2*1H;/q;;+2/p |
InChI key | AXZWODMDQAVCJE-UHFFFAOYSA |
mp | 246 °C (lit.) |
pH | 2.18 (20 °C) |
Quality Level | 200 |
SMILES string | Cl[SnH2]Cl |
vapor pressure | 33 hPa (~429 °C) |
Application: | Tin(II) chloride (SnCl2) has been used as a starting material to evaluate the thermal behavior of SnCl2 on heating at the rate of 5°Cmin-1 in air. The product undergoes phase transformation on heating at rate of 5°C min-1 in air, it involves an incomplete evaporation followed by oxidation forming SnO2 nanoparticles. SnCl2 has also been used for the fabrication of Sn-containing carbon nano-structures. |
Application: | Tin(II) chloride may be used: • To catalyze the addition of diazo sulfones, diazo phosphine oxides and diazo phosphonates to aldehydes to form β-keto sulfones, β-keto phosphine oxides and β-keto phosphonates, respectively. • Along with trityl chloride, to catalyze the aldol reaction of silyl enol ethers with acetals or aldehydes and the Michael reaction of silyl enol ethers with α,β-unsaturated ketones. • As a promoter in the allylic amination of allylic alcohols with amines in the presence of palladium catalyst. |
General description: | SnCl2 dihydrate reacts with acetic anhydride to yield anhydrous SnCl2. SnCl2 exhibits reducing properties in acidic media. SnCl2 shows superior catalytic action in its molten state. It is a promising raw material for the chemical vapour deposition (CVD) of semiconducting layers. SnCl2 participates in the reduction of aromatic nitro compounds, nitriles, cyanosilyl ethers and organic azides. |
Packaging: | 100, 500 g in poly bottle |
Packaging: | 2 kg in poly bottle |
Symbol | GHS05,GHS07,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H290 - H302 + H332 - H314 - H317 - H335 - H373 - H410 |
Precautionary statements | P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
Hazard Codes | C,N |
Risk Statements | 63-20-34-43-48/22-50/53-68 |
Safety Statements | 53-26-36/37/39-45-60-61 |
RIDADR | UN3260 - class 8 - PG 2 - EHS - Corrosive solid, acidic, inorgan |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 98% |
bp | 652 °C (lit.) |
mp | 246 °C (lit.) |
UNSPSC | 12352300 |