Magnesium perchlorate

SIGALD/222283 - ACS reagent

CAS Number: 10034-81-8
Empirical Formula (Hill Notation): Cl₂MgO₈
Molecular Weight: 223.21
EC Number: 233-108-3
MDL Number: MFCD00011102
Linear Formula: Mg(ClO₄)₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-222283-5G	5 g	$0.00 1/EA CALL FOR PRICEAdd To Favorites		Add To Favorites
45-222283-100G	100 g	$108.00 1/EAAdd To Favorites		Add To Favorites
45-222283-500G	500 g	$319.00 1/EAAdd To Favorites		Add To Favorites

concentration	>10% Mg (EDTA titration)
form	flakes
	powder, chunks or granules
grade	ACS reagent
impurities	≤0.005 meq/g Titr. free acid
	≤0.025 meq/g Titr. base
InChI	1S/2ClHO4.Mg/c22-1(3,4)5;/h2(H,2,3,4,5);/q;;+2/p-2
InChI key	MPCRDALPQLDDFX-UHFFFAOYSA-L
loss	≤8% loss on drying
Quality Level	200
reaction suitability	reagent type: oxidant
SMILES string	[Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
suitability	passes test for moisture absorption

Application:	Magnesium perchlorate (Mg(ClO₄)₂) may be employed as a catalyst in the following studies: • Preparation of α-aminophosphonates. • Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one. • Preparation of imines and phenylhydrazones. • Protection of alcohols in the form of t-butyl ethers.
Application:	Magnesium perchlorate may be used as a catalyst in the synthesis of the following compounds: • α-Aminophosphonates via three-component reaction between an amine, an aldehyde or a ketone and a di-/trialkyl phosphite. • Imines and phenylhydrazones by the condensation of carbonyl compounds with amines and phenylhydrazine. • Knoevenagel adducts via Knoevenagel condensation between β-diketones and aliphatic or aromatic aldehydes. It may also be used to catalyze the protection of alcohols as t-butyl ethers.
General description:	Magnesium perchlorate (Mg(ClO₄)₂) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.
Packaging:	100 g in poly bottle
Packaging:	5 g in glass bottle
Packaging:	500 g in glass bottle

Symbol	GHS03,GHS07
Signal word	Danger
Hazard statements	H272 - H315 - H319 - H335
Precautionary statements	P210 - P302 + P352 - P305 + P351 + P338
Hazard Codes	O,Xi
Risk Statements	8-36/37/38
Safety Statements	7/8-17-26-27-36/37/39
RIDADR	UN 1475 5.1 / PGII
WGK Germany	WGK 1
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable