Sodium hypochlorite solution
SIGALD/239305 - reagent grade, available chlorine 4.00-4.99 %
CAS Number: 7681-52-9
Empirical Formula (Hill Notation): ClNaO
Molecular Weight: 74.44
EC Number: 231-668-3
MDL Number: MFCD00011120
Linear Formula: NaClO
Product Type: Chemical
| agency | suitable for SM 4500 - NH3 |
| composition | available chlorine, 4.00-4.99% |
| concentration | 4.00-4.99% (chlorine by Na2S2O3, titration) |
| density | 1.097 g/mL at 25 °C |
| form | liquid |
| grade | reagent grade |
| InChI | 1S/ClO.Na/c1-2;/q-1;+1 |
| InChI key | SUKJFIGYRHOWBL-UHFFFAOYSA |
| Quality Level | 100  |
| reaction suitability | reagent type: oxidant |
| SMILES string | [Na+].[O-]Cl |
| storage temp. | 2-8°C |
| vapor pressure | 17.5 mmHg ( 20 °C) |
| Application: | Sodium hypochlorite solution can be used as an oxidizing agent for the oxidation of: • Primary alcohols to aldehydes or carboxylic acids and secondary alcohols to ketones. • Aryl aldehydes to the corresponding acids in the presence of a phase-transfer catalyst. • Ethers to esters by careful pH control (pH range of 8–9.5), It can also be used as a reagent in the: • Epoxidation of enones and polycyclic arenes. • Oxidative degradation reaction • N-Chlorination of primary and secondary amines • Enantioselective epoxidation of α, β-unsaturated ketones • Asymmetric dihydroxylation of olefins in the presence of an osmium catalyst • Chlorination of allylic carbons in the presence of CeCl3 |
| Disclaimer: | “The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others.” |
| Features and Benefits: | • Readily available reagent • Easily handled oxidizing agent • No phase-transfer catalyst is necessary for the oxidation of substrates in the pH range 10–11 • Simplified waste disposal and lower toxicity |
| General description: | Sodium hypochlorite (NaOCl) is a commonly used reagent in organic synthesis for many oxidation and chlorination reactions. |
| Packaging: | 25, 500 mL in poly bottle |
| Packaging: | 4 L in poly drum |
| Symbol |   GHS05,GHS09,GHS05,GHS09 |
| Signal word | Danger-Danger |
| Hazard statements | H315 - H318 - H400 - H315 - H318 - H410 |
| Precautionary statements | P264 - P273 - P280 - P264 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P302 + P352 - P305 |
| Hazard Codes | N |
| Risk Statements | 50 |
| Safety Statements | 61 |
| RIDADR | UN 3082 9 / PGIII |
| WGK Germany | WGK 2 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Density | 1.097 g/mL at 25 °C |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352300 |