Titanium(IV) chloride
SIGALD/254312 - ≥99.995% trace metals basis
Synonym: TTC; Titanium tetrachloride
CAS Number: 7550-45-0
Empirical Formula (Hill Notation): Cl4Ti
Molecular Weight: 189.68
EC Number: 231-441-9
MDL Number: MFCD00011267
Linear Formula: TiCl4
Product Type: Chemical
| assay | ≥99.995% trace metals basis |
| bp | 135-136 °C (lit.) |
| 136.4 °C | |
| density | 1.73 g/mL at 20 °C (lit.) |
| form | liquid |
| InChI | 1S/4ClH.Ti/h4*1H;/q;;;;+4 |
| InChI key | XJDNKRIXUMDJCW-UHFFFAOYSA |
| mp | −25 °C (lit.) |
| Quality Level | 100  |
| reaction suitability | reagent type: catalyst core: titanium |
| SMILES string | Cl[Ti](Cl)(Cl)Cl |
| vapor pressure | 50 mmHg ( 55 °C) |
| 9.6 mmHg ( 20 °C) |
| Application: | Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines. |
| Application: | Promotes a highly selective aldol reaction of (S)-2-benzyloxy-3-pentanone in THF or DME. |
| Application: | Titanium(IV) chloride has been used in the synthesis of anatase TiO2 structures with macropores (250nm in diameter) and mesoscale pores (50nm in diameter). |
| General description: | Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide. |
| Packaging: | 10, 50 g in glass bottle |
| Symbol |   GHS05,GHS06 |
| Signal word | Danger |
| Hazard statements | H314 - H330 - H335 |
| Precautionary statements | P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| Hazard Codes | T,C |
| Risk Statements | 14-23-34-39/23-48/23 |
| Safety Statements | 7/8-26-36/37/39-45 |
| RIDADR | UN 1838 8 |
| WGK Germany | WGK 1 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Supplemental Hazard Statements | EUH014 |
| Purity | ≥99.995% trace metals basis |
| bp | 135-136 °C (lit.); 136.4 °C |
| mp | −25 °C (lit.) |
| Density | 1.73 g/mL at 20 °C (lit.) |
| UNSPSC | 12352300 |