Cobalt(II) chloride hexahydrate
SIGALD/255599 - ACS reagent, 98%
Synonym: Cobaltous chloride hexahydrate
CAS Number: 7791-13-1
Empirical Formula (Hill Notation): Cl2Co · 6H2O
Molecular Weight: 237.93
EC Number: 231-589-4
MDL Number: MFCD00149652
Linear Formula: CoCl2 · 6H2O
Product Type: Chemical
anion traces | nitrate (NO3-): ≤0.01% |
sulfate (SO42-): ≤0.01% | |
assay | 98% |
98.0-102.0% (ACS specification) | |
cation traces | Ca: ≤0.005% |
Cu: ≤0.002% | |
Fe: ≤0.005% | |
K: ≤0.01% | |
Mg: ≤0.005% | |
Na: ≤0.05% | |
Ni: ≤0.1% | |
Zn: ≤0.03% | |
form | powder, crystals or chunks |
grade | ACS reagent |
impurities | ≤0.01% insolubles |
InChI | 1S/2ClH.Co.6H2O/h2*1H;;6* |
InChI key | GFHNAMRJFCEERV-UHFFFAOYSA |
Quality Level | 200 |
reaction suitability | reagent type: catalyst core: cobalt |
SMILES string | O.O.O.O.O.O.Cl[Co]Cl |
vapor pressure | 40 mmHg ( 0 °C) |
Application: | Cobalt(II) chloride hexahydrate can be used as a catalyst for the: • Dioxygenation of styrenes with N-hydroxyphthalimide to synthesize corresponding alcohols and ketones. • Oxidative coupling of primary amines to imines. • Friedel-Crafts reaction between indoles and activated olefins to synthesize β-indolylketones. • Synthesis of β-enaminones and β-enamino esters. • Reaction of acyl chlorides with diselenides or disulfides to synthesize selenol and thiol esters. |
General description: | Cobalt(II) chloride hexahydrate, also known as cobaltous chloride hexahydrate, is a hydrated form of cobalt and chloride. It is a crystalline solid consisting of octahedral complexes, with the coordination polyhedron of the Co2+ ion including four H2O molecules and two Cl− ions. It is highly soluble in water and is commonly used as a catalyst in various organic synthesis, such as during the synthesis of benzimidazole and biscoumarin derivatives. |
Packaging: | 100, 500 g in poly bottle |
Packaging: | 5 g in glass bottle |
Symbol | GHS07,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H302 - H317 - H334 - H341 - H350i - H360F - H410 |
Precautionary statements | P273 - P280 - P301 + P312 - P302 + P352 - P304 + P340 + P312 - P308 + P313 |
Hazard Codes | T,N |
Risk Statements | 49-60-22-42/43-50/53-68 |
Safety Statements | 53-45-60-61 |
RIDADR | UN 3077 9 / PGIII |
WGK Germany | WGK 2 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 98%; 98.0-102.0% (ACS specification) |
UNSPSC | 12352300 |