Ammonium chloride
SIGALD/31107 - puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5%
Synonym: Salmiac
CAS Number: 12125-02-9
Empirical Formula (Hill Notation): H4ClN
Molecular Weight: 53.49
EC Number: 235-186-4
MDL Number: MFCD00011420
Linear Formula: NH4Cl
Product Type: Chemical
agency | reag. ISO |
reag. Ph. Eur. | |
USP/NF | |
anion traces | nitrate (NO3-): ≤5 mg/kg |
phosphate (PO43-): ≤2 mg/kg | |
sulfate (SO42-): ≤20 mg/kg | |
assay | ≥99.5% |
cation traces | As: ≤0.5 mg/kg |
Ca: ≤5 mg/kg | |
Cu: ≤2 mg/kg | |
Fe: ≤2 mg/kg | |
heavy metals: ≤5 ppm (by ICP-OES) | |
K: ≤50 mg/kg | |
Mg: ≤5 mg/kg | |
Na: ≤50 mg/kg | |
Ni: ≤1 mg/kg | |
Pb: ≤1 mg/kg | |
Zn: ≤2 mg/kg | |
form | crystalline powder |
grade | ACS reagent |
puriss. p.a. | |
InChI | 1S/ClH.H3N/h1H;1H3 |
InChI key | NLXLAEXVIDQMFP-UHFFFAOYSA |
mp | 340 °C (subl.) (lit.) |
pH | 4.5-5.5 (20 °C, 5%) |
Quality Level | 200 |
SMILES string | N.Cl |
vapor density | 1.9 (vs air) |
vapor pressure | 1 mmHg ( 160.4 °C) |
Application: | Ammonium chloride can be used as a catalyst: • To synthesize 3,4-dihydropyrimidin-2-(1H)-ones via solvent-free Biginelli-condensation reaction. • For the aldol condensation of carbonyl compounds. • In the thia-Michael addition reaction of thiols to different α-enones. It can also be used as:• A promoter in the enantioselective hydrogenation of an unprotected β-enamine amides. • A pH-adjuster in the preparation of waterborne glucose silicone resin. |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H302 - H319 |
Precautionary statements | P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P337 + P313 |
Hazard Codes | Xn |
Risk Statements | 22-36 |
Safety Statements | 22 |
WGK Germany | WGK 1 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥99.5% |
mp | 340 °C (subl.) (lit.) |
UNSPSC | 12352300 |