Bismuth(III) nitrate pentahydrate
SIGALD/383074 - ACS reagent, ≥98.0%
CAS Number: 10035-06-0
Empirical Formula (Hill Notation): BiN3O9 · 5H2O
Molecular Weight: 485.07
EC Number: 233-791-8
Linear Formula: Bi(NO3)3 · 5H2O
Product Type: Chemical
anion traces | chloride (Cl-): ≤0.001% |
sulfate (SO42-): ≤0.005% | |
assay | ≥98.0% |
bp | 75-80 °C (lit.) |
cation traces | Ag: ≤0.001% |
As: ≤0.001% | |
Ca: ≤0.005% | |
Cu: ≤0.002% | |
Fe: ≤0.001% | |
K: ≤0.01% | |
Na: ≤0.02% | |
Pb: ≤0.002% | |
form | (Powder or Crystals or Solid or Chunks) |
grade | ACS reagent |
impurities | ≤0.005% insolubles |
InChI | 1S/CH4.Bi.3NO3/c;;3*2-1(3 |
InChI key | DPLOIMSBRDLLRI-UHFFFAOYSA |
mp | 30 °C (lit.) |
Quality Level | 200 |
reaction suitability | reagent type: catalyst core: bismuth |
SMILES string | O=[N+](O[Bi](O[N+]([O-])= |
Application: | Bismuth(III) nitrate pentahydrate may be used in the following processes: • Conversion of thioamides and thioureas to their oxo derivatives. • Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions. • Synthesize coumarins by Pechmann condensation under solvent free conditions. • As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics. • As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrob • As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives. • Synthesis of glycosides by Fischer glycosylation of unprotected sugars. • Synthesis of bismuth oxide (Bi2O3) nanoparticles. • Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines. • Selective oxidation of sufides to sulfoxides. |
General description: | Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications. |
Packaging: | 100, 500 g in poly bottle |
Symbol | GHS03,GHS05 |
Signal word | Danger |
Hazard statements | H272 - H318 |
Precautionary statements | P210 - P220 - P280 - P305 + P351 + P338 - P370 + P378 - P501 |
Hazard Codes | O,Xi |
Risk Statements | 8-36/37/38 |
Safety Statements | 17-26-36 |
RIDADR | UN 1477 5.1 / PGII |
WGK Germany | WGK 2 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥98.0% |
bp | 75-80 °C (lit.) |
mp | 30 °C (lit.) |
UNSPSC | 12352300 |