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Bismuth(III) nitrate pentahydrate

SIGALD/383074 - ACS reagent, ≥98.0%

CAS Number: 10035-06-0
Empirical Formula (Hill Notation): BiN3O9 · 5H2O
Molecular Weight: 485.07
EC Number: 233-791-8
Linear Formula: Bi(NO3)3 · 5H2O
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-383074-100G 100 g
$66.90
1/EA
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45-383074-500G 500 g
$220.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 383074-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 383074-500G

 

anion traces chloride (Cl-): ≤0.001%
  sulfate (SO42-): ≤0.005%
assay ≥98.0%
bp 75-80 °C (lit.)
cation traces Ag: ≤0.001%
  As: ≤0.001%
  Ca: ≤0.005%
  Cu: ≤0.002%
  Fe: ≤0.001%
  K: ≤0.01%
  Na: ≤0.02%
  Pb: ≤0.002%
form (Powder or Crystals or Solid or Chunks)
grade ACS reagent
impurities ≤0.005% insolubles
InChI 1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1
InChI key DPLOIMSBRDLLRI-UHFFFAOYSA-N
mp 30 °C (lit.)
Quality Level 200 
reaction suitability reagent type: catalyst
core: bismuth
SMILES string O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C
Application: Bismuth(III) nitrate pentahydrate may be used in the following processes:
• Conversion of thioamides and thioureas to their oxo derivatives.
• Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions.
• Synthesize coumarins by Pechmann condensation under solvent free conditions.
• As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics.
• As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation.
• As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives.
• Synthesis of glycosides by Fischer glycosylation of unprotected sugars.
• Synthesis of bismuth oxide (Bi2O3) nanoparticles.
• Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines.
• Selective oxidation of sufides to sulfoxides.
General description: Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.
Packaging: 100, 500 g in poly bottle
Purity ≥98.0%
bp 75-80 °C (lit.)
mp 30 °C (lit.)
UNSPSC 12352300

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