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Dimethyl sulfoxide

SIGALD/41640 - puriss. p.a., ACS reagent, ≥99.9% (GC)

Synonym: DMSO; DMSO

CAS Number: 67-68-5
Empirical Formula (Hill Notation): C2H6OS
Molecular Weight: 78.13
EC Number: 200-664-3
MDL Number: MFCD00002089
Linear Formula: (CH3)2SO
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-41640-100ML 100 mL
$109.00
1/EA
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45-41640-500ML 500 mL
$185.00
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45-41640-1L 1 L
$233.00
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45-41640-2.5L 2.5 L
$368.00
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assay ≥99.9% (GC)
autoignition temp. 573 °F
bp 189 °C (lit.)
cation traces Al: ≤0.5 mg/kg
  Ba: ≤0.1 mg/kg
  Bi: ≤0.1 mg/kg
  Ca: ≤0.5 mg/kg
  Cd: ≤0.05 mg/kg
  Co: ≤0.02 mg/kg
  Cr: ≤0.02 mg/kg
  Cu: ≤0.02 mg/kg
  Fe: ≤0.5 mg/kg
  K: ≤0.5 mg/kg
  Li: ≤0.1 mg/kg
  Mg: ≤0.1 mg/kg
  Mn: ≤0.02 mg/kg
  Mo: ≤0.1 mg/kg
  Na: ≤1 mg/kg
  Ni: ≤0.5 mg/kg
  Pb: ≤0.1 mg/kg
  Sr: ≤0.1 mg/kg
  Zn: ≤0.1 mg/kg
density 1.10 g/mL (lit.)
evapn. residue ≤0.005%
expl. lim. 42 %, 63 °F
form liquid
grade ACS reagent
  puriss. p.a.
impurities ≤0.001% free acid (as CH3COOH)
  ≤0.1% water
InChI 1S/C2H6OS/c1-4(2)3/h1-2H3
InChI key IAZDPXIOMUYVGZ-UHFFFAOYSA-N
mp 16-19 °C (lit.)
  18-20 °C
Quality Level 300 
refractive index n20/D 1.479
  n20/D 1.479 (lit.)
SMILES string CS(C)=O
vapor density 2.7 (vs air)
vapor pressure 0.42 mmHg ( 20 °C)
Application:

  • Modification of gelatin by reaction with 1,6-diisocyanatohexane.: This study focuses on the modification of biopolymers using chemical agents, which could be relevant in contexts where DMSO is used as a reaction solvent ( Bertoldo et al., 2007 ).

  • Characterization of O-acetyl-(4-O-methylglucurono)xylan isolated from birch and beech.: This research characterizes specific wood-derived xylans, potentially enhancing understanding of such biopolymers when dissolved in DMSO for analytical studies ( Teleman et al., 2002 ).

Caution: Supercools easily and remelts slowly at room temperature. Solidified product can be re-liquified by warming to room temperature without detriment to the product.
General description: Dimethyl sulfoxide (DMSO) is a polar solvent. DMSO activated by electrophile (oxalyl chloride) has been used to oxidize various alcohols (primary, secondary, allylic, benzylic, hindered and bicyclic). Carbonyl compounds are formed as reaction products. It has been proposed as an alternate solvent for methyl cellosolve for use in ninhydrin reaction, due to its high stability.
Other Notes: For information on dimethyl sulfoxide miscibility, please visit the following link:
Dimethyl Sulfoxide Miscibility/Immiscibility Table 
Other Notes: Use as reagent in synthesis
WGK Germany WGK 1
Flash Point(F) 188.6 °F - closed cup
Flash Point(C) 87 °C - closed cup
Purity ≥99.9% (GC)
bp 189 °C (lit.)
mp 16-19 °C (lit.); 18-20 °C
Density 1.10 g/mL (lit.)
Refractive Index n20/D 1.479 (lit.); n20/D 1.479
UNSPSC 12191502

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