Lithium bromide
SIGALD/746479 - anhydrous, free-flowing, Redi-Dri™, ReagentPlus®, ≥99%
CAS Number: 7550-35-8
Empirical Formula (Hill Notation): BrLi
Molecular Weight: 86.85
EC Number: 231-439-8
MDL Number: MFCD00011077
Linear Formula: LiBr
Product Type: Chemical
assay | ≥99% |
form | powder |
grade | anhydrous |
InChI | 1S/BrH.Li/h1H;/q;+1/p-1 |
InChI key | AMXOYNBUYSYVKV-UHFFFAOYSA |
mp | 550 °C (lit.) |
pH | 7 (20 °C, 10 g/L) |
product line | ReagentPlus® |
Redi-Dri™ | |
quality | free-flowing |
Quality Level | 100 |
SMILES string | [Li+].[Br-] |
vapor pressure | 1 hPa ( 748 °C) |
Application: | Lithium bromide can be used as a catalyst in the:• Solvent-free condensation of arylene diamines and esters to synthesize 2-substituted benzimidazoles and imidazopyridines. • Three-component condensation of aldehydes, β-ketoesters, and urea to synthesize dihydropyrimidinones via Biginelli reaction. • Solvent-free Ehrlich-Sachs reaction. |
General description: | Lithium bromide is a versatile reagent that is commonly used as a nucleophilic brominating reagent. It is also employed as a Lewis acid catalyst and a mediator in various reactions. |
Legal Information: | ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany |
Legal Information: | Redi-Dri is a trademark of Sigma-Aldrich Co. LLC |
Packaging: | 1, 2.5 kg in poly bottle |
Packaging: | 100, 500 g in poly bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H302 - H315 - H317 - H319 |
Precautionary statements | P261 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xn |
Risk Statements | 22-36/38-43 |
Safety Statements | 22-24/25-26-36/37/39-60 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 1 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥99% |
mp | 550 °C (lit.) |
UNSPSC | 12352302 |