Tetrahydrofuran
SIGALD/87368 - contains 250 ppm BHT as inhibitor, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.9%
Synonym: THF; Butylene oxide; Oxolane; Tetramethylene oxide
CAS Number: 109-99-9
Empirical Formula (Hill Notation): C4H8O
Molecular Weight: 72.11
EC Number: 203-726-8
MDL Number: MFCD00005356
Linear Formula: C4H8O
Product Type: Chemical
| agency | reag. Ph. Eur. |
| assay | ≥99.9% |
| autoignition temp. | 610 °F |
| bp | 65-67 °C (lit.) |
| cation traces | Al: ≤0.5 mg/kg |
| B: ≤0.02 mg/kg | |
| Ba: ≤0.1 mg/kg | |
| Bi: ≤0.1 mg/kg | |
| Ca: ≤0.5 mg/kg | |
| Cd: ≤0.05 mg/kg | |
| Co: ≤0.02 mg/kg | |
| Cr: ≤0.02 mg/kg | |
| Cu: ≤0.02 mg/kg | |
| Fe: ≤0.1 mg/kg | |
| K: ≤0.5 mg/kg | |
| Li: ≤0.1 mg/kg | |
| Mg: ≤0.1 mg/kg | |
| Mn: ≤0.02 mg/kg | |
| Mo: ≤0.1 mg/kg | |
| Na: ≤0.5 mg/kg | |
| Ni: ≤0.02 mg/kg | |
| Pb: ≤0.1 mg/kg | |
| Sn: ≤0.1 mg/kg | |
| Sr: ≤0.1 mg/kg | |
| Zn: ≤0.1 mg/kg | |
| contains | 250 ppm BHT as inhibitor |
| ~0.025% 2,6-di-tert-butyl-4-methy |
|
| density | 0.887 g/mL at 20 °C |
| 0.889 g/mL at 25 °C (lit.) | |
| evapn. residue | ≤0.001% |
| expl. lim. | 1.8-11.8 % |
| form | liquid |
| grade | ACS reagent |
| puriss. p.a. | |
| impurities | ≤0.001% free acid (as CH3COOH) |
| ≤0.005% peroxides (as H2O2) | |
| ≤0.05% water | |
| InChI | 1S/C4H8O/c1-2-4-5-3-1/h1- |
| InChI key | WYURNTSHIVDZCO-UHFFFAOYSA |
| mp | −108 °C (lit.) |
| pH | ~7 |
| Quality Level | 200 ![]() |
| refractive index | n |
| n |
|
| SMILES string | C1CCOC1 |
| technique(s) | solid phase extraction (SPE): suitable |
| vapor density | 2.5 (vs air) |
| vapor pressure | 114 mmHg ( 15 °C) |
| 143 mmHg ( 20 °C) |
| Analysis Note: | miscible with water and ethanol (96%) pass |
| Application: | Tetrahydrofuran has been used as a solvent for the preparation of sol-gel solution for coating solid phase microextraction (SPME) fibers in a study. It may be used for the dissolution of poly-ε-caprolactone (PCL) and 1,3-diaminopentane, during the preparation of poly-ε-caprolactone (PCL)-hydroxyapatite (HA) scaffolds and acrylate-terminated poly(5-amino-1-pentanol-c |
| General description: | The product is tetrahydrofuran (THF) and it contains 250ppm BHT (Butylated hydroxytoluene) as an inhibitor. THF is widely employed as a solvent. It constitutes the key fragment of various natural products (polyether antibiotics). THF forms double hydrate with hydrogen sulfide. Crystal structure of this double hydrate has been investigated by three-dimensional single-crystal studies. Butane-1,4-diol is formed as an intermediate during the synthesis of THF. Hot THF is useful for the dissolution of polyvinylidene chloride (PVDV). |
| Other Notes: | Go to our Greener Alternative-2-Methyl Tetrahydrofuran - 155810 ![]() Go to our Greener Alternative-Cyclopentyl methylether - 675989 ![]() |
| Other Notes: | Sales restrictions may apply |
| Other Notes: | The article number 87368-6X1L-M will be discontinued. Please order the single bottle 87368-1L-M which is physically identical with the same exact specifications. |
| Symbol | ![]() ![]() GHS02,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225 - H302 - H319 - H335 - H336 - H351 |
| Precautionary statements | P201 - P202 - P210 - P301 + P312 - P305 + P351 + P338 - P308 + P313 |
| Hazard Codes | F,Xn |
| Risk Statements | 11-19-36/37-40 |
| Safety Statements | 13-16-29-33-36-37-46 |
| RIDADR | UN 2056 3 / PGII |
| WGK Germany | WGK 1 |
| Flash Point(F) | -6.2 °F - closed cup |
| Flash Point(C) | -21.2 °C - closed cup |
| Supplemental Hazard Statements | EUH018 - EUH019 |
| Purity | ≥99.9% |
| bp | 65-67 °C (lit.) |
| mp | −108 °C (lit.) |
| Density | 0.887 g/mL at 20 °C; 0.889 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352005 |




