Sodium (meta)periodate
SIGALD/S1878 - ≥99.0%
Synonym: Sodium periodate
CAS Number: 7790-28-5
Empirical Formula (Hill Notation): INaO4
Molecular Weight: 213.89
EC Number: 232-197-6
MDL Number: MFCD00003534
Linear Formula: NaIO4
Product Type: Chemical
assay | ≥99.0% |
form | powder |
InChI | 1S/HIO4.Na/c2-1(3,4)5;/h( |
InChI key | JQWHASGSAFIOCM-UHFFFAOYSA |
pH | 3.5-5.5 (25 °C, 107 g/L) |
Quality Level | 300 |
reaction suitability | reagent type: oxidant |
SMILES string | [Na+].[O-]I(=O)(=O)=O |
solubility | H2O: 50 mg/mL |
Application: | Sodium (meta)periodate can be used as an oxidizing agent for the oxidation of: • 1,2-diols to aldehydes or ketones via oxidative cleavage. Sulfides to sulfoxides in the presence of phase transfer catalysts. • Diaryl, dialkyl, and aryl alkyl selenides to the respective selenoxides. • Phenols and their derivatives to corresponding quinones. • Acylphosphoranes to α,β-dicarbonyl compounds. It can also be used in the: • Selective alkene epoxidation and alkane hydroxylation,· • Oxidation of carbohydrates. • Iodination of aromatic compounds. |
Application: | Useful reagent for the oxidation of carbohydrates prior to labeling with biotin hydrazide |
Features and Benefits: | NaIO4 is a stable, selective, and cost-effective reagent that is capable of reacting under mild conditions. |
General description: | Sodium (meta)periodate is commonly used as an oxidizing agent in organic synthesis for the oxidation of various organic substrates. It can also be used as a co-oxidant with other oxidizing reagents such as osmium tetroxide and potassium permanganate. The oxidation of sodium periodate takes place in a water medium, but an organic co-solvent is used for organic substrates that are insoluble in water. |
Packaging: | 25, 100, 500 g in glass bottle |
Symbol | GHS03,GHS05,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H271 - H314 - H372 - H410 |
Precautionary statements | P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | O,T,C,N |
Risk Statements | 8-34-48/25-50 |
Safety Statements | 17-26-36/37/39-61 |
RIDADR | UN3085 - class 5.1 - PG 1 - acidic - EHS - Oxidizing solid, corr |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥99.0% |
UNSPSC | 12352300 |